69243-59-0Relevant academic research and scientific papers
Iodine mediated direct coupling of benzylic alcohols with dithiocarbamate anions: An easy access of S-benzyl dithiocarbamate esters under neat reaction condition
Dutta, Soumya,Saha, Amit
, (2020/09/10)
An efficient, metal and solvent free synthesis of S-benzylic dithiocarbamate esters has been demonstrated via the iodine mediated direct C-S coupling of benzylic alcohols with dithiocarbamate anions generated in-situ by the reactions of amines and carbon disulphide. All the reactions were very fast (15–30 min) and performed under open air atmosphere. Cyclic and acyclic secondary amines, primary amine, aromatic amine actively participated in the one-pot coupling reactions with different benzylic alcohols. Non benzylic alcohols offer the synthesis of O-thiocarbamate compounds under the identical reaction condition.
Facile one pot synthesis of a range of reversible addition-fragmentation chain transfer (RAFT) agents
Skey, Jared,O'Reilly, Rachel K.
supporting information; experimental part, p. 4183 - 4185 (2009/03/11)
The application of a universal synthetic strategy for the high yielding and facile synthesis of a wide range of functional RAFT agents including trithiocarbonates, xanthates and dithiocarbamates is described. The Royal Society of Chemistry.
