69245-96-1

Upstream product

• 69245-95-0 4-(1-Cyclohexenyl)-3-carbethoxy-2-butanon 
• 4430-31-3 octahydrocoumarin 
• 64-19-7 acetic acid 
• 699-61-6 1-oxaspiro[4.5]decan-2-one 
• 636-82-8 cyclohexene-1-carboxylic acid 
• 37677-17-1 1-bromomethylcyclohexene 
• 55106-53-1 1-bromocyclohexanecarboxylic acid 
• 4845-04-9 1-cyclohexene-1-methanol 
• 54709-77-2 2,2-diethoxy-4-phenylbutane 
• 74-89-5 methylamine 

Downstream Products

• 83912-58-7 (Z)-5-Cyclohex-1-enyl-3-methyl-pent-2-enoic acid ethyl ester 
• 83912-41-8 (E)-5-Cyclohex-1-enyl-3-methyl-pent-2-enoic acid ethyl ester 
• 97845-94-8 (Z)-Ethyl 4-<4-(1-cyclohexenyl)-2-methyl-1-butenyl>benzoate 
• 97845-93-7 (E)-Ethyl 4-<4-(1-cyclohexenyl)-2-methyl-1-butenyl>benzoate 

Relevant academic research and scientific papers

PROCESS FOR THE DIRECT CONVERSION OF LACTONES INTO UNSATURATED KETONES OR ALDEHYDES

The present invention refers to a process for the preparation of unsaturated ketones or aldehydes by pyrolysis of a lactone, in the presence of a reducing agent such as molecular hydrogen or a carboxylic acid, and in the presence of a catalyst, optionally

Unsymmetrical unsaturated ketones from lactones and carboxylic acids in one step

A one-step transformation of γ- and δ-(spiro)lactones into γ,δ- and δ,ε-unsaturated ketones in the presence of carboxylic acids in the vapor phase at 400° over a supported manganese catalyst is reported for the first time. The scope of this new transformation is exemplified with a series of lactones, and a mechanistic rationale is proposed.