69657-27-8

Basic information

• Product Name: (S)-4-(4-methylphenyl)pentan-2-one
• Synonyms: (S)-4-(4-methylphenyl)pentan-2-one
• CAS NO: 69657-27-8
• Molecular Weight: 176.258
• Mol File: 69657-27-8.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: (S)-4-(4-methylphenyl)pentan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4-(4-methylphenyl)pentan-2-one(69657-27-8)
• EPA Substance Registry System: (S)-4-(4-methylphenyl)pentan-2-one(69657-27-8)

Safety Data

• Hazardous Substances Data: 69657-27-8(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 3160-38-1 (E)-4-p-tolylbut-3-en-2-one 
• 94853-53-9 ethyl 3-(4-methylphenyl)-2-butenoate 
• 80352-30-3 (E)-4-(p-tolyl)-3-penten-2-one 
• 122-00-9 para-methylacetophenone 
• 1569-50-2 3-penten-2-ol 
• 459-44-9 4-methylbenzenediazonium tetrafluoroborate 
• 14062-19-2 p-tolylacetic acid ethyl ester 
• 1257661-37-2 (S)-1-methyl-4-(pent-4-en-2-yl)benzene 
• 1413723-26-8 (R)-1-iodo-2-(4-methylphenyl)propane 
• 122091-54-7 (R)-(+)-2-(4-methylphenyl)propanol 
• 131605-39-5 (R)-3-hydroxy-2-(4-methylphenyl)propyl acetate 
• 4424-32-2 2-(4-methylphenyl)-1,3-propanediol 
• 29148-27-4 diethyl 2-(4-methylphenyl)propane-1,3-dioate 

Downstream Products

• 532-65-0 (+)-(S)-ar-turmerone 
• 109650-88-6 (S)-ar-turmerone semicarbazone 
• 97372-50-4 Methyl (S)-(+)-5-(3'-methoxy-4'-methylphenyl)hexanoate 
• 97372-48-0 (S)-3-(4-Methyl-3-nitro-phenyl)-butyric acid 
• 88948-12-3 (S)-5-(3-Methoxy-4-methyl-phenyl)-hexanoic acid 
• 97329-87-8 Methyl (S)-(+)-3-methoxycurcumate 
• 97372-49-1 (S)-3-(3-Methoxy-4-methyl-phenyl)-butyric acid 
• 97329-89-0 (S)-3-(3'-Methoxy-4'-methylphenyl)-butanal 
• 97329-88-9 (3S)-3-(3-Methoxy-4-methylphenyl)butan-2-ol 
• 17701-23-4 (+)-curcumone semicarbazone 

Relevant articles and documents

Pseudo enantiomeric mixed S/P ligands derived from carbohydrates for the 1,4-addition of phenyl boronic acid to cyclohexenone

The application of phosphinite-thioglycosides and phosphine-thioglycosides ligands in Rh(i)-catalyzed 1,4-addition of phenylboronic acid to cyclohexenone is reported. Among the ligands tested, phosphinite-thioglycoside 3 and phosphine-thioglycoside 10, be

Chiral-Anion-Mediated Asymmetric Heck-Matsuda Reaction of Acyclic Alkenyl Alcohols

Acyclic internal alkenes are a class of challenging substrates in asymmetric Heck-type reactions due to difficulties related to both reactivity and selectivity control. Employing acyclic alkenyl alcohols, an asymmetric Heck-Matsuda reaction is developed through the strategy of chiral anion phase transfer. Various chiral ketones could be obtained in high levels of enantioselectivity. A catalytic amount of dimethyl sulfoxide (DMSO) as an additive is crucial for the reaction to suppress the palladium-hydride-mediated side reactions.

Electronically deficient (Rax,S,S)-F12-C3-TunePhos and its applications in asymmetric 1,4-addition reactions

A novel electronically deficient chiral diphosphine ligand (Rax,S,S)-F12-C3-TunePhos has been concisely synthesized. The electron-poor ligand features both chiral centers and chiral axis bearing fluoro-functional groups on