696660-32-9

Upstream product

• 770-12-7 O-phenyl phosphorodichloridate 
• 752232-62-5 (+)-cis-N,N'-dibenzyl-1,2,2-trimethylcyclopentane-1,3-diamine 
• 116481-14-2 (1R,3S)-1,2,2-trimethyl-1,3-cyclopentanediamine 
• 108-95-2 phenol 
• 124-83-4 D-(+)-camphoric acid 

Relevant academic research and scientific papers

Synthesis of some new chiral bifunctional o-hydroxyarylphosphonodiamides and their application as ligands in Ti(IV) complex catalyzed asymmetric silylcyanation of aromatic aldehydes

Some new chiral bifunctional o-hydroxyarylphosphonodiamides were synthesized starting from (+)-cis-1,2,2-trimethylcyclopentane-1,3-diamine and the absolute configuration of the phosphorus atom was determined by X-ray diffraction analysis. Excellent enantioselectivity (up to 98% ee) was achieved in asymmetric silylcyanation of aromatic aldehydes using a chiral titanium complex formed in situ from Ti(OiPr)4 and o-hydroxyarylphosphonodiamide as the catalyst. Graphical Abstract.