6967-82-4

Usage

Chemical Properties

Off-white powder

InChI:InChI=1/C8H7BrO2/c1-5-2-3-7(9)6(4-5)8(10)11/h2-4H,1H3,(H,10,11)

Upstream product

• 60956-26-5 4-bromo-2-nitrotoluene 
• 151-50-8 potassium cyanide 
• 42872-83-3 2-bromo-5-methylbenzylnitrile 
• 99-04-7 m-Toluic acid 
• 2941-78-8 2-Amino-5-methylbenzoic acid 
• 7726-95-6 bromine 

Downstream Products

• 861133-95-1 1,1-dimethylethyl (3-endo)-[({[(2-bromo-5-methylphenyl)amino]arbonyl}oxy)methyl]-8-azabicyclo[3.2.1]octane-8-carboxylate 
• 1310071-28-3 2-methyl-6-phenylbenzo[4,5]imidazo[1,2-c]quinazoline 
• 1301148-93-5 C₁₄H₁₁BrN₂ 
• 21419-51-2 6-methyl-2-phenylquinazolin-4(3H)-one 
• 82256-07-3 6-methyl-2-(4-methylphenyl)-4(3H)-quinazolinone 
• 1401880-57-6 N-benzyl-2-bromo-5-methylbenzamide 
• 1048108-06-0 2-bromo-N-methoxy-N,5-dimethylbenzamide 

Relevant academic research and scientific papers

Formation of Benzo[ b ]Thiophenes by Electroreduction of Tert-Alkanecarbodithioates

The electroreduction of a 1:1-mixture of 2-bromobenzyl 2,2-dimethylpropanedithioate and 2-bromo-5-methylbenzyl 2,2-dimethylbutanedithioate led to a mixture of 2-Tert-butylbenzo[b]thiophene, 2-Tert-Amylbenzo[b]thiophene, 2-Tert-butyl-5-methylbenzo[b]thioph

PdII-catalyzed monoselective ortho halogenation of C-H bonds assisted by counter cations: A complementary method to directed ortho lithiation

(Chemical Equation Presented) When the counterion counts: The yield and selectivity of the title transformation of benzoic acid derivatives were improved greatly by using tetraalkyl ammonium salts as additives (see scheme; monoselectivity: 5:1-18:1). These effects are attributed to the influence of counter cations. The halogenated products are versatile intermediates for the construction of substituted aromatic compounds. DMF=N,N-dimethylformamide.