69762-72-7Relevant academic research and scientific papers
A NOVEL ROUTE TO ALDEHYDIC ENOL ETHERS AND ENAMINES
Gilbert, J. C.,Weerasooriya, U.
, p. 2041 - 2044 (1980)
Base-promoted reaction of dimethyl diazomethylphosphonate (1) with dialkyl and cyclic ketones in the presence of alcohols and of amines affords aldehydic enol ethers and enamines, respectively.
Rhodium(III)/Amine Synergistically Catalyzed Enantioselective Alkylation of Aldehydes with α,β-Unsaturated 2-Acyl Imidazoles
Gong, Jun,Li, Kuan,Qurban, Saira,Kang, Qiang
supporting information, p. 1225 - 1235 (2016/12/28)
A synergistic catalysis combination of chiral-at-metal rhodium complex and amine catalyst was developed for enantioselective alkylation of aldehydes with α,β-unsaturated 2-acyl imidazoles. The corresponding adducts were obtained in good yields with excellent enantioselectivities (up to 99% ee).
Fluorocyanation of enamines
Dilman, Alexander D.,Belyakov, Pavel A.,Struchkova, Marina I.,Arkhipov, Dmitry E.,Korlyukov, Alexander A.,Tartakovsky, Vladimir A.
supporting information; experimental part, p. 5367 - 5370 (2010/10/21)
(Figure presented) A method for the fluorocyanation of enamines has been described. The reaction involves fluorination of the electron rich double bond with N-F reagent (Selectfluor or NFSI) accompanied by trapping of β-fluoroiminium cationic intermediate with cyanide nucleophile.
Generation of Aldehydic Enol Ethers and Enamines by Olefination of Ketones
Gilbert, John C.,Weerasooriya, Upali
, p. 448 - 453 (2007/10/02)
Reaction of aliphatic ketones with dimethyl (diazomethyl)phosphonate (5, R = CH3) in the presence of alcohols and amines afforded enol ethers and enamines, respectively, of the next higher aldehyde.The technique has been found to be applicable to several
