70026-36-7

Usage

Uses

Used in Chemical Ecology:
PHENYL-D5-ACETONITRILE is used as a chemical marker for the detection of Light brown apple moth larvae infestations in apple trees. The presence of PHENYL-D5-ACETONITRILE can indicate the presence of the pest, allowing for timely intervention and management strategies to protect the apple crop.
Used in Pest Management:
PHENYL-D5-ACETONITRILE is used as a tool in the development of pest management strategies for apple growers. By understanding the chemical signatures of infested trees, growers can implement targeted control measures to reduce the impact of the Light brown apple moth on their crops.
Used in Research and Development:
PHENYL-D5-ACETONITRILE is used as a research compound to study the chemical communication and behavior of the Light brown apple moth. This knowledge can contribute to the development of novel pest control methods, such as pheromone-based traps or other biocontrol strategies.
Used in Analytical Chemistry:
PHENYL-D5-ACETONITRILE can be used as an internal standard or reference compound in analytical chemistry, particularly in the analysis of volatile organic compounds in the environment or in the study of plant-pest interactions. Its unique properties and stable isotopic labeling make it a valuable tool for accurate quantification and identification of target compounds.

Upstream product

• 35656-93-0 perdeuteriobenzyl bromide 
• 143-33-9 sodium cyanide 
• 68661-11-0 5>Benzylchlorid 
• 151-50-8 potassium cyanide 
• 2037-26-5 ⁽²⁾H₈-toluene 
• 4165-57-5 bromobenzene-d5 
• 215527-70-1 2,3,4,5,6-pentadeuteriumbenzeneboronic acid 
• 590-17-0 cyanomethyl bromide 
• 56253-90-8 L-(δ1,δ2,ε1,ε2,ζ-2H5)-phenylalanine 

Downstream Products

• 1419174-64-3 C₁₀H₆⁽²⁾H₅N 
• 912627-98-6 [2,3,4,5,6‐D₅]phenylethyl isothiocyanate 
• 216966-11-9 phenyl-d5 acetic chloride 

Relevant academic research and scientific papers

Synthesis of stable isotope-labeled nasturlexins and potential precursors to probe biosynthetic pathways of cruciferous phytoalexins

The syntheses of perdeuterated phytoalexins nasturlexins A and C, and putative biosynthetic precursors, including phenylethyl isothiocyanates and phenylethyl dithiocarbamates, using commercially available [2,3,4,5,6-D5]phenylalanine, [2,3,4,5,6

Palladium-Catalyzed Regioselective C-H Alkenylation of Arylacetamides via Distal Weakly Coordinating Primary Amides as Directing Groups

Herein we disclose the efficient Pd(II)-catalyzed and regioselective ortho C-H alkenylation of arylacetamide derivatives, viz. weakly coordinating aliphatic primary amides. This protocol utilizes ubiquitous free primary amides as the directing group and c

Synthesis of indolines by copper-mediated intramolecular aromatic C-H amination

A Cu(OAc)2-mediated intramolecular aromatic C-H amination proceeds with the aid of a picolinamide-type bidentate coordination group to deliver the corresponding indolines in good yields. The reaction occurs smoothly even under noble-metal-free conditions, and in some cases the use of an MnO2 terminal oxidant renders the process catalytic in Cu. The mild oxidation aptitude of Cu(OAc)2 and/or MnO2 accommodates the formation of electron-rich thiophene-and indole-fused indoline analogues. The Cu-based system can provide an effective approach to various indolines of potent interest in pharmaceutical and medicinal chemistry.

EPR investigation of persistent radicals produced from the photolysis of dibenzyl ketones adsorbed on ZSM-5 zeolites

Photolysis of ketones (1, 1-oMe, 2, 2-oMe, 3, and 4) adsorbed on ZSM-5 zeolites produces persistent carbon-centered radicals that can be readily observed by conventional steady-state EPR spectroscopy. The radicals are persistent for time periods of seconds to many hours depending on the supramolecular structure of the initial radical@zeolite complex and the diffusion and reaction dynamics of radicals produced by photolysis. The structures of the persistent radicals responsible for the observed EPR spectra are determined by a combination of alternate methods of generation of the same radical, by deuterium substitution, and by spectral simulation. A clear requirement for persistence is that the radicals produced by photolysis must either separate and diffuse from the external to the internal surface or be generated within the internal surface and separate and diffuse apart. The persistence of radicals located on the internal surface is the result of inhibition of radical-radical reactions. Radicals that are produced on the external surface and whose molecular structure prevents diffusion into the internal surface are transient because radical-radical reactions occur rapidly on the external surface. The reactions of the persistent radicals with oxygen and nitric oxide were directly studied in situ by EPR analysis. In the case of reaction with oxygen, persistent peroxy radicals are formed in high yield. The addition of nitric oxide scavenges persistent radicals and leads initially to a diamagnetic nitroso compound, which is transformed into a persistent nitroxide radical by further photolysis. The influence of variation of radical structure on transience/persistence is discussed and correlated with supramolecular structure and reactivity of the radicals and their parent ketones.

Photolysis of alkylhalodiazirines and direct observation of benzylchlorocarbene in cryogenic matrices

Photolysis of 3-benzyl-3-chlorodiazirine and its deuterated homologues 3-chloro-3-(phenyldideuteriomethyl)diazirine and 3-chloro-3-((pentadeuteriophenyl)methyl)diazirine has been investigated by means of IR and UV-vis spectroscopy in argon and xenon matri