70076-04-9Relevant academic research and scientific papers
MOLECULES HAVING CERTAIN PESTICIDAL UTILITIES, AND INTERMEDIATES, COMPOSITIONS, AND PROCESSES RELATED THERETO
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Page/Page column 74; 231, (2021/02/12)
This disclosure relates to compounds having pesticidal utility against pests in phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such compounds and intermediates used in such processes, compositions containing such compounds, and processes of using such compounds against such pests. These compounds/molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses compounds having the following formula (Formula One and/or Formula One-A).
Scalable Synthesis of Acridinium Catalysts for Photoredox Deuterations
Fischer, Christian,Schneider, Lukas,Sparr, Christof,Zilate, Bouthayna
, p. 4359 - 4365 (2019/11/21)
The continuous development of photocatalytic methods incentivizes the design of organic catalysts to complement the frequently used and precious polypyridyl transition metal systems. Herein, a scalable synthesis of suitable acridinium dyes and their appli
Direct Transformation of Esters into Heterocyclic Fluorophores
Fischer, Christian,Sparr, Christof
supporting information, p. 2436 - 2440 (2018/02/06)
Despite the manifold use of heterocyclic fluorophores, only a fraction of the desired dye diversity can be accessed by contemporary synthetic approaches. Herein, we describe a modular method that converts various carboxylic acid esters directly into a bro
Mono-nitration of aromatic compounds via nitrate salts
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Page/Page column 2; 11, (2008/06/13)
A method of nitrating a compound selected from the group consisting of is provided.
Mono-nitration of aromatic compounds via their nitric acid salts
Zhang, Pingsheng,Cedilote, Miall,Cleary, Thomas P.,Pierce, Michael E.
, p. 8659 - 8664 (2008/03/30)
Aromatic compounds bearing a basic nitrogen atom can be converted to the corresponding nitric acid salts. Mono-nitration of the compounds can be carried out by adding a dichloromethane solution of the salts to sulfuric acid, or by adding acetyl chloride (or trifluoroacetic anhydride) to a dichloromethane solution of the salts. This protocol provides, among other benefits, the most convenient and reliable way for the prevention of over-/under-nitration and is especially suitable for scale-up.
A novel tunable aromatic bromination method using alkyl bromides and sodium hydride in DMSO
Guo, MaoJun,Varady, Laszlo,Fokas, Demosthenes,Baldino, Carmen,Yu, Libing
, p. 3889 - 3892 (2007/10/03)
Aromatic bromination on various aromatic systems with different substitutions was performed in the presence of alkyl bromide and sodium hydride in DMSO. Mono-bromination on a wide range of substrates was achieved by selecting proper alkyl bromides and controlling its amount. Further bromination could happen with more active alkyl bromides and additional amount of bromides and sodium hydride. The yields ranged from moderate to excellent. In addition, reaction mechanism was postulated to explain our observations.
