70094-91-6

Upstream product

• 100-52-7 benzaldehyde 
• 19713-73-6 methyl (2Z)-3-phenylprop-2-enoate 
• 108009-65-0 threo-2,3-Bis(trimethylsiloxy)-3-phenylpropansaeure-trimethylsilylester 
• 103-26-4 methyl cinnamate 
• 69-96-5 dl-threo-phenylserine 
• 140-10-3 (E)-3-phenylacrylic acid 

Downstream Products

• 55449-78-0 (2S,3S)-2,3-dihydroxy-3-phenyl-propionic acid 
• 55449-79-1 (2S,3R)-2,3-dihydroxy-3-phenyl-propionic acid 
• 56816-81-0 (2R,3S)-2,3-dihydroxy-3-phenyl-propionic acid 
• 156-06-9 2-oxo-3-(phenyl)propionic acid 
• 133520-58-8 [1-((4S,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-meth-(Z)-ylidene]-((R)-2-methoxymethyl-pyrrolidin-1-yl)-amine 
• 133421-03-1 [1-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-meth-(Z)-ylidene]-((R)-2-methoxymethyl-pyrrolidin-1-yl)-amine 
• 133421-02-0 erythro-2,2-Dimethyl-5-phenyl-1,3-dioxolan-4-carbonsaeure-ethylester 
• 133521-66-1 (4S,5R)-Ethyl 2,2-dimethyl-5-phenyl-1,3-dioxolane-4-carboxylate 
• 130718-77-3 (4R,5R)-cis-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-carbaldehyde 
• 130796-32-6 (4S,5R)-trans-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-carbaldehyde 
• 16354-93-1 (1R,2R)-1-phenylpropane-1,2,3-triol 
• 81691-61-4 Toluene-4-sulfonic acid (4S,5S)-2,2-dimethyl-5-phenyl-[1,3]dioxolan-4-ylmethyl ester 
• 81691-62-5 9-(RS)-threo-(2,3-O-isopropylidene-3-phenyl-2,3-dihydroxypropyl)adenine 
• 81691-63-6 9-(RS)-threo-(2-phenyl-2,3-dihydroxypropyl)adenine 

Relevant academic research and scientific papers

Lewis base activation of Lewis acids: Catalytic enantioselective glycolate aldol reactions

(Chemical Equation Presented) Both syn- and anti-1,2-diols can be obtained with high diastereoselectivity and enantioselectivity from the properly substituted glycolate-derived silyl ketene acetals in the presence of SiCl 4 and a chiral bisphos

Reactions of Trialkylsilyl Trifluoromethanesulfonates VII. - α-Trimethylsiloxycarboxylation by Tris(trimethylsiloxy)ethene.

In the presence of trimethylsilyl triflate (1), acetals and orthocarboxylic acid esters 3 react with tris(trimethylsiloxy)ethene 2 to yield 3-alkoxy- and 3,3-dialkoxy-2-(trimethylsiloxy)carboxylates 4.From carbonyl compounds 6 and the ketene acetal 2 2,3-

Kinetics and Mechanism of the Oxidation of Unsaturated Carboxylic Acids by Methyltributylammonium Permanganate in Methylene Chloride Solutions

The product obtained when permanganate is reduced by unsaturated carboxylic acids under anhydrous conditions is manganese(III).The rate of reaction, which is subject to acid catalysis, exhibits a Hammet ρ value of 1.11 and inverse secondary isotope effects (kH/kD = 0.96-0.98) when the hydrogens on the double bond are replaced by deuterium.The involvement of a free-radical process is indicated by the formation of polymer during the oxidation of acrylic and methacrylic acids.The reaction is believed to be initiated by formation of an organometallic complex in which the double bond is a η2 ligand on manganese.Rearrangement of this complex results in the formation of a reactive manganate(V) cyclic diester, which undergoes a rapid (free-radical) reduction to manganese(III).