70150-56-0

Basic information

• Product Name: 4-hydroxy-4-methylcyclohex-2-en-1-one
• Synonyms: 2-Cyclohexen-1-one, 4-hydroxy-4-methyl-
• CAS NO: 70150-56-0
• Molecular Formula: C₇H₁₀O₂
• Molecular Weight: 126.1531
• Mol File: 70150-56-0.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 242.9°C at 760 mmHg
• Flash Point: 99.6°C
• Density: 1.129g/cm³
• Vapor Pressure: 0.00561mmHg at 25°C
• Refractive Index: 1.513
• CAS DataBase Reference: 4-hydroxy-4-methylcyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 4-hydroxy-4-methylcyclohex-2-en-1-one(70150-56-0)
• EPA Substance Registry System: 4-hydroxy-4-methylcyclohex-2-en-1-one(70150-56-0)

Safety Data

• Hazardous Substances Data: 70150-56-0(Hazardous Substances Data)

Upstream product

• 911817-23-7 4-hydroperoxy-4-methylcyclohex-2-en-1-one 
• 4683-24-3 1,4-dioxa-spiro[4.5]dec-6-en-8-one 
• 33082-74-5 8-Methyl-1,4-dioxa-spiro[4.5]dec-6-en-8-ol 
• 20023-36-3 2,5-dihydro-4-methylanisole 
• 5259-65-4 4-methyl-3-cyclohexen-1-one 
• 104-93-8 p-methylanizole 
• 82873-58-3 1-acetyl-4-methyl-3-cyclohexen-1-ol 
• 23438-23-5 4-hydroxy-4-methyl-cyclohexa-2,5-dienone 
• 512-85-6 ascaridole 

Downstream Products

• 138371-83-2 2-(5-bromo-2-methoxyphenyl)-4-methylcyclohex-2-en-1-one 
• 138371-82-1 4-(4-bromo-2-methoxyphenyl)-4-methylcyclohex-2-en-1-one 
• 138371-81-0 2-(5-bromo-2-methoxyphenyl)-4-fluoro-4-methylcyclohexanone 
• 99432-86-7 4-methyl-4-(4-methoxyphenyl)-cyclohex-2-en-1-one 
• 138371-78-5 2-(4-methoxyphenyl)-1-methylcyclohex-3-en-1-one 
• 138371-80-9 4-fluoro-2-(4-methoxyphenyl)-4-methylcyclohexane 
• 138371-79-6 4-(2-methoxyphenyl)-4-methylcyclohex-2-en-1-one 
• 138371-77-4 4-fluoro-4-methyl-2-(p-tolyl)-cyclohexanone 
• 138371-74-1 4-methyl-4-(p-tolyl)cyclohex-2-en-1-one 
• 138371-76-3 4-methyl-2-(p-tolyl)cyclohex-3-en-1-one 
• 84602-27-7 3-Acetylcyclopentanone 
• 138371-84-3 6-(5-bromo-2-methoxyphenyl)-4-methylcyclohex-2-en-1-one 
• 138371-75-2 4-methyl-4-para-tolylcyclohexanone 
• 17429-36-6 4-methyl-4-phenylcyclohex-2-enone 

Relevant articles and documents

Synthesis of the reported structure of pogostol and a total synthesis of (±)-kessane without the use of protecting groups

(Matrix presented) A short racemic synthesis of kessane from 4-hydroxy-4-methyl-2-cyclohexenone is described using a route that also resulted in the synthesis of the reported structure of pogostol. The key step involves an Fe(III)-mediated tandem radical

Substituent effect on the photochemistry of 4,4-dialkoxylated- and 4-hydroxylated cyclohexenones

Photochemistry of the title compounds in various solvents was studied using a broad band of light centered at 350 nm. C-4 spiroketal cyclohexenone 4 (1.0 M) afforded dimers and 12b with the predominance of the former in polar solvent and the latter in non

Synthesis of 4-hydroxy-4-methylcyclohex-2-en-1-one

4-Hydroxy-4-methylcyclohex-2-en-1-one was synthesised from 4-methylanisole. The key step is the regioselective reaction of singlet oxygen with 4-methylcyclohex-3-en-1-one.