70207-45-3

Upstream product

• 619-73-8 4-nitrobenzyl chloride 
• 814-49-3 diethyl chlorophosphate 

Downstream Products

• 1817-77-2 4-benzyl-1-nitrobenzene 
• 3145-86-6 4-nitrobenzyl iodide 
• 70207-47-5 3,6-bis(4-nitrostyryl)-9-ethyl carbazole 
• 1075218-63-1 4-[2-(4-iodo-phenyl)-vinyl]-phenylamine 
• 2844-15-7 N,N-dimethyl-4-[(E)-2-(4-nitrophenyl)vinyl]aniline 
• 22525-43-5 trans-4′-(N,N′-dimethylamino)-4-aminostilbene 
• 1075218-64-2 4-[2-(4-tributylstannanylphenyl)vinyl]phenylamine 
• 7314-06-9 (E)-4,4'-diaminostilbene 
• 1075218-61-9 N-methyl-{4-[2-(4-amino-phenyl)-vinyl]-phenyl}-amine 
• 1075218-62-0 (E)-4-iodostyrylnitrobenzene 
• 736-31-2 trans-4,4'-dinitrostilbene 
• 18648-70-9 1,1-diphenyl-2-(4-nitrophenyl)ethene 

Relevant academic research and scientific papers

Suzuki-Miyaura cross-coupling of benzylic phosphates with arylboronic acids

(Chemical Equation Presented) Suzuki-Miyaura cross-coupling of benzylic phosphates with arylboronic acids was investigated. Optimum conditions employed the simple catalytic system of palladium(II) acetate (1 mol %) and triphenylphosphine (4 mol %) with either potassium phosphate or potassium carbonate as the base and toluene as the solvent at 90°C. Using the developed conditions, a series of structurally diverse diarylmethanes were prepared.

Pd-Catalyzed Coupling of N-Tosylhydrazones with Benzylic Phosphates: Toward the Synthesis of Di- or Tri-Substituted Alkenes

This study shows that various di- and tri-substituted alkenes with high chemoselectivity were obtained in good to high yields by coupling N-tosylhydrazones (NTHs) with benzylic phosphates as electrophilic partners. The obtained new catalytic system consis

Synthesis of diarylmethanes through palladium-catalyzed coupling of benzylic phosphates with arylsilanes

An efficient approach to the benzylation of arenes has been developed. The reactions described provide straightforward access to diarylmethanes through Pd-catalyzed coupling of benzylic phosphates with arylsilanes in good to excellent yields. The reaction tolerates a wide range of functionalities such as halide, alkoxyl, and nitro groups.