70303-26-3Relevant articles and documents
Iron Catalyzed Isomerization of α-Alkyl Styrenes to Access Trisubstituted Alkenes
Xu, Songgen,Liu, Guixia,Huang, Zheng
, p. 585 - 589 (2021/02/01)
Stereoselective isomerization of α-alkyl styrenes is accomplished using a new iron catalyst supported by phosphine-pyridine-oxazoline (PPO) ligand. The protocol provides an atom-efficient and operationally simple approach to trisubstituted alkenes in high
Stereoretentive Pd-catalyzed kumada-corriu couplings of alkenyl halides at room temperature
Krasovskiy, Arkady L.,Haley, Stephen,Voigtritter, Karl,Lipshutz, Bruce H.
supporting information, p. 4066 - 4069 (2014/10/15)
Stereoselective palladium-catalyzed Kumada-Corriu reactions of functionalized alkenyl halides and a variety of Grignard reagents, including those bearing β-hydrogen atoms and sensitive functional groups, can be carried out at room temperature using a new combination of reagents.
Sulfoxides in Julia-Lythgoe olefination: Efficient and stereoselective preparation of di-, tri-, and tetrasubstituted olefins
Pospisil, Jiri,Pospisil, Tomas,Marko, Istvan E.
, p. 2373 - 2376 (2007/10/03)
(Chemical Equation Presented) A novel modification of the classical Julia-Lythgoe olefination, using sulfoxides instead of sulfones, affords, after in situ benzoylation and Sml2/HMPA- or DMPU-mediated reductive elimination, 1,2-di-, tri-, and tetrasubstituted olefins in moderate to excellent yields and E/Z selectivity. The conditions are mild, and the procedure is broadly applicable.