704-79-0

Basic information

• Product Name: 2-Butenoic acid, 3-phenyl-, (Z)-
• CAS NO: 704-79-0
• Molecular Formula: C10H10O2
• Molecular Weight: 162.188
• Mol File: 704-79-0.mol
• Article Data: 31

Chemical Properties

• CAS DataBase Reference: 2-Butenoic acid, 3-phenyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenoic acid, 3-phenyl-, (Z)-(704-79-0)
• EPA Substance Registry System: 2-Butenoic acid, 3-phenyl-, (Z)-(704-79-0)

Safety Data

• Hazardous Substances Data: 704-79-0(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 124-38-9 carbon dioxide 
• 121-69-7 N,N-dimethyl-aniline 
• 98-83-9 isopropenylbenzene 
• 552-82-9 benzhydrylidene(methyl)amine 
• 1504-72-9 ethyl 3-phenylbut-2-enoate 
• 15226-74-1 dicobalt octacarbonyl 
• 16917-35-4 (E)-(1-bromoprop-1-en-2-yl)benzene 
• 3724-65-0 2-butenoic acid 
• 917-54-4 methyllithium 
• 637-44-5 phenylpropyolic acid 
• 65946-59-0 (trimethylsilyl)ketene bis(trimethylsilyl) acetal 
• 591-50-4 iodobenzene 
• 107-93-7 (E)-but-2-enoic acid 

Downstream Products

• 4593-90-2 3-phenylbutyric acid 
• 80854-59-7 β-methyl-4-nitrocinnamic acid 
• 102548-30-1 2,3-dibromo-3-phenyl-butyric acid 
• 98-83-9 isopropenylbenzene 
• 704-80-3 (E)-3-phenyl-2-butenoic acid 
• 52393-68-7 (Z)-3-methyl-N-phenylcinnamamide 
• 7386-65-4 (Z)-3-phenylbut-2-enamide 
• 20698-78-6 (+/-)-3-Methoxy-3-phenyl-buttersaeure 
• 76076-42-1 (S)-2-Benzyloxymethyl-1-((Z)-3-phenyl-but-2-enyl)-pyrrolidine 
• 3360-55-2 β-chloro-α-methylstyrene 
• 70453-19-9 (E)-3-phenylbut-2-enoyl chloride 
• 68204-17-1 (Z)-3-phenylbut-2-enoyl chloride 
• 772-14-5 (R)-3-phenylbutyric acid 
• 4593-90-2 (S)-2-phenylbutanoic acid 

Relevant articles and documents

Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed [3 + 2] Annulation of Vinyl Enolates with 1-Tosyl-2-vinylaziridine

The synergistic combination of N-heterocyclic carbene organocatalysis and transition-metal catalysis for a formal [3 + 2] annulation between 3-substituted but-2-enoates and 1-tosyl-2-vinylaziridine was developed. This cooperative strategy provides a facile and efficient access to various functionalized (E)-3-ethylidene-4-vinylpyrrolidin-2-ones in a regioselective and stereoselective manner. The preliminary asymmetric studies were also performed, which indicated a potential for enantioselective annulation of vinyl enolate intermediates with transition-metal-π-allyl species.

Synthesis of 6-hydroxy-5,6-dihydro-2-pyrones and -pyridones by reaction of 4-aryl-6-trifluoromethyl-2-pyrones with water, hydrazine, and hydroxylamine

[Figure not available: see fulltext.] Reactions of 4-aryl-6-trifluoromethyl-2H-pyran-2-ones with sodium hydroxide followed by acidification provided the respective 6-hydroxy-5,6-dihydro derivatives, while the reactions of 4-aryl-6-trifluoromethyl-2H-pyran

Iridium(III)-catalyzed regioselective direct arylation of sp2 C-H bonds with diaryliodonium salts

A regioselective direct arylation of arenes and olefins at the ortho position is reported. The key to the high selectivity is the appropriate choice of diaryliodonium salts as the arylating reagent in the presence of a cationic iridium(iii) catalyst. The coordination of the metal with an oxygen atom or a nitrogen atom and subsequent C-H activation allows for direct arylation with coupling partners. This reaction proceeds under mild reaction conditions and with a high tolerance of various functional groups including many halide functional groups.