70458-22-9

Upstream product

• 54322-65-5 cyclopropylacetyl chloride 
• 937-14-4 3-chloro-benzenecarboperoxoic acid 
• 5239-82-7 cyclopropylacetic acid 

Downstream Products

• 53477-27-3 4-<4-(N,N-Dimethylamino)benzyl>-N-methylaniline 
• 101-61-1 4,4'-methylene-bis(N,N-dimethylaniline) 
• 125303-00-6 2-But-3-enyl-N¹,N¹,N⁴,N⁴-tetramethyl-benzene-1,4-diamine 
• 125302-99-0 2-Cyclopropylmethyl-N¹,N¹,N⁴,N⁴-tetramethyl-benzene-1,4-diamine 

Relevant academic research and scientific papers

Decarboxylative Borylation of mCPBA-Activated Aliphatic Acids

A decarboxylative borylation of aliphatic acids for the synthesis of a variety of alkylboronates has been developed by mixing m-chloroperoxybenzoic acid (mCPBA)-activated fatty acids with bis(catecholato)diboron in N,N-dimethylformamide (DMF) at room temperature. A radical chain process is involved in the reaction which initiates from the B-B bond homolysis followed by the radical transfer from the boron atom to the carbon atom with subsequent decarboxylation and borylation.

RADICAL AND IONIC REACTION PATHWAYS IN THE THERMAL DECOMPOSITION OF DIACYL PEROXIDES1.

Thermolysis of peroxides 5a,b and 11a,b has demonstrated that the cyclobutyl and cyclopropylmethyl groups are very sensitive structural probes of post-transition-state events in diacyl peroxide decomposition. Analysis of product mixtures indicates that es