708-66-7Relevant academic research and scientific papers
Selective oxidation and chlorination of trifluoromethylsulfide using trichloroisocyanuric acid in ionic liquid
Tang, Ri-Yuan,Zhong, Ping,Lin, Qiu-Lian
, p. 636 - 640 (2008/01/06)
A route to chemoselective oxidation and chlorination of aryltrifluoromethylsulfide using trichloroisocyanuric acid (TCCA) in ionic liquid, an efficiently O-methylation reaction and a reduction of nitro- to amido- in excellent yields have been developed.
Method for condensation of aromatic derivative(s) and a sulphinic derivative
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, (2008/06/13)
The invention concerns a method for the condensation of aromatic derivative(s) or a sulphinic derivative by a perhalogenated, advantageously perfluorinated, carbon atom. Said method is characterized in that it consists in subjecting said sulphinic derivat
Nucleophilic trifluoromethylation of organic substrates using (trifluoromethyl)trimethylsilane in the presence of a fluoride anion. II. A convenient route to aryltrifluoromethyl-sulfides, - sulfoxides and -sulfones
Movchun, Valeria N.,Kolomeitsev, Alexander A.,Yagupolskii, Yurii L.
, p. 255 - 258 (2007/10/02)
Aryltrifluoromethyl-sulfides, -sulfoxides and -sulfones can be prepared by trifluoromethylation of the corresponding arylsulfenyl, -sulfinyl and -sulfonyl halides using (trifluoromethyl)trimethylsilane in the presence of fluoride sources, such as TASF . - Keywords: Nucleophilic trifluoromethylation; (Trifluoromethyl)trimethylsilane; Fluoride anion; Aryltrifluoromethylsulfides; Aryltrifluoromethylsulfoxides; Aryltrifluoromethylsulfones
FLUORO(TRIFLUOROMETHYL)ARYLSULFONIUM AND (TRIFLUOROMETHYL)DIARYLSULFONIUM SALTS
Yagupol'skii, L. M.,Kondratenko, N. V.,Timofeeva, G. N.
, p. 103 - 106 (2007/10/02)
The oxygen atoms in aryl trifluoromethyl sulfoxides are substituted by fluorine during the action of the SF3(1+)*BF4(1-) and SF3(1+)*SbF6(1-) complexes.Fluoro(trifluoromethyl)arylsulfonium and (trifluoromethyl)diarylsulfonium salts were synthesized.The la
