7152-80-9

Basic information

• Product Name: 4-(DIMETHYLAMINO)PHENYL THIOCYANATE
• Synonyms: 4-Dimethylaminophenylthiocyanate;4-dimethylaminothiocyanobenzene;4-thiocyano-n,n-dimethylaniline;defoliant2929rp;dimethylamino-4-thiocyanobenzene;dimethylaminorhodanbenzol;n,n-dimethyl-p-thiocyanato-anilin;p-(dimethylamino)phenylthiocyanate
• CAS NO: 7152-80-9
• Molecular Formula: C₉H₁₀N₂S
• Molecular Weight: 178.2541
• Mol File: 7152-80-9.mol
• Article Data: 67

Chemical Properties

• Boiling Point: 303.6°C at 760 mmHg
• Flash Point: 137.4°C
• Appearance: /
• Density: 1.1355 (rough estimate)
• Vapor Pressure: 0.000918mmHg at 25°C
• Refractive Index: 1.5300 (estimate)
• CAS DataBase Reference: 4-(DIMETHYLAMINO)PHENYL THIOCYANATE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(DIMETHYLAMINO)PHENYL THIOCYANATE(7152-80-9)
• EPA Substance Registry System: 4-(DIMETHYLAMINO)PHENYL THIOCYANATE(7152-80-9)

Safety Data

• Hazardous Substances Data: 7152-80-9(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthetic Communications, 25, p. 1277, 1995 DOI: 10.1080/00397919508012691

InChI:InChI=1/C9H10N2S/c1-11(2)8-3-5-9(6-4-8)12-7-10/h3-6H,1-2H3

Upstream product

• 121-69-7 N,N-dimethyl-aniline 
• 163276-49-1 1-thiocyanatopyrrolidine-2,5-dione 
• 5397-29-5 4-(N,N-dimethylamino)phenyl disulfide 
• 151-50-8 potassium cyanide 
• 2987-46-4 4-thiocyanatoaniline 
• 74-88-4 methyl iodide 
• 592-87-0 lead(II) thiocyanate 
• 1147550-11-5 ammonium thiocyanate 
• 540-72-7 sodium thiocyanide 
• 333-20-0 potassium thioacyanate 
• 60763-20-4 selenium dithiocyanate 
• 2959-01-5 N,N'-dichloro-urea 
• 5961-98-8 thiocyanatochloride 
• 56-23-5 tetrachloromethane 

Downstream Products

• 92331-91-4 (4-Hexylsulfanyl-phenyl)-dimethyl-amine 
• 62291-62-7 N,N-dimethyl-4-(benzylthio)benzenamine 
• 42881-80-1 N,N-dimethyl-4-(phenylthio)aniline 
• 4946-22-9 N,N-dimethyl-4-aminothiophenol 
• 333-20-0 potassium thioacyanate 
• 68253-26-9 4-(4-chlorophenylthio)-N,N-dimethylbenzenamine 
• 68253-25-8 4-((4-fluorophenyl)thio)-N,N-dimethylaniline 
• 1044572-72-6 [4-(4-chloro-benzenesulfinyl)phenyl]dimethylamine 
• 2677-71-6 N,N-dimethyl-4-[(trifluoromethyl)thio]benzeneamine 
• 1309446-24-9 2-((4-(dimethylamino)phenyl)sulfinyl)-5-fluorobenzonitrile 
• 1309446-23-8 4-((4-fluoro-2-(pent-1-yn-1-yl)phenyl)sulfinyl)-N,N-dimethylaniline 
• 1309446-22-7 4-((5-fluoro-4'-methoxy-[1,1'-biphenyl]-2-yl)sulfinyl)-N,N-dimethylaniline 
• 1309446-21-6 2'-((4-(dimethylamino)phenyl)sulfinyl)-5'-fluoro-[1,1'-biphenyl]-4-carbonitrile 
• 1309446-20-5 4-((4-chloro-2-((trimethylsilyl)ethynyl)phenyl)sulfinyl)-N,N-dimethylaniline 

Relevant articles and documents

Two-step synthesized sulfonic acid functionalized imidazolium thiocyanate solid acid catalyst for thiocyanation of various electron rich arenes by metal-free method in water

An eco-friendly, highly efficient, and novel sulfonic acid functionalized imidazolium thiocyanate (Imidazole-SO3H)/SCN and sulfonic acid functionalized imidazolium chloride (Imidazole-SO3H)/Cl solid acid catalyst were successfully synthesized. The structure of catalyst was characterized by various analyses such as FT-IR, 1H NMR and 13C NMR spectroscopy. The thiocyanation reaction of various electron rich arenes such as anilines, indoles, phenols, and other aromatic compounds were selected to show the catalytic performance and efficiency of the as-prepared solid acid catalyst, and excellent yields of the corresponding aryl and heteroaryl thiocyanates derivatives were obtained under metal-free and green conditions in water. In addition, one of the important features of current method is when the thiocyanation reaction is carried out with (Imidazole-SO3H)/SCN, this reagent has a dual role in the reaction, both as thiocyanation agent and as acidic group. On the other hand, (Imidazole-SO3H)/Cl as a catalyst plays just as acidic group in reaction. The current procedure offers advantages such as metal-free and green conditions, simple procedure, the use of a commercially available reagent, simple reaction work-up, ease of separation using simple filtration, and suitable performance in the reusability of the catalyst.

Selective electrochemical: Para -thiocyanation of aromatic amines under metal-, oxidant- And exogenous-electrolyte-free conditions

An electrochemical oxidative para-C-H-thiocyanation of aromatic amines has been developed to construct thiocyanato aromatic compounds under metal-, oxidant-, and exogenous-electrolyte-free conditions in an undivided cell. The transformation is compatible

Visible light-induced recyclable g-C3N4catalyzed thiocyanation of C(sp2)-H bonds in sustainable solvents

A metal-free photocatalytic strategy for the preparation of thiocyanated heterocycles from inexpensive NH4SCN has been developed using carbon nitride (g-C3N4) as a general heterogeneous catalyst in a green solvent under an