2987-46-4

Basic information

• Product Name: 4-AMINOPHENYL THIOCYANATE
• Synonyms: AKOS B029033;4-AMINOPHENYL THIOCYANATE;4-Thiocyanatoaniline;Thiocyanic acid, 4-aminophenyl ester (9CI);1-Amino-4-thiocyanatobenzene;4-Thiocyanobenzenamine;(4-azanylphenyl) thiocyanate;thiocyanic acid (4-aminophenyl) ester
• CAS NO: 2987-46-4
• Molecular Formula: C₇H₆N₂S
• Molecular Weight: 150.2
• EINECS: 233-118-8
• Product Categories: AMINEPRIMARY;API Intermediate
• Mol File: 2987-46-4.mol
• Article Data: 58

Chemical Properties

• Melting Point: 142°C
• Boiling Point: 314.5°C at 760 mmHg
• Flash Point: 144°C
• Appearance: /
• Density: 1.2162 (rough estimate)
• Vapor Pressure: 0.000465mmHg at 25°C
• Refractive Index: 1.5500 (estimate)
• PKA: 2.94±0.10(Predicted)
• Water Solubility: 0.2g/L(temperature not stated)
• CAS DataBase Reference: 4-AMINOPHENYL THIOCYANATE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-AMINOPHENYL THIOCYANATE(2987-46-4)
• EPA Substance Registry System: 4-AMINOPHENYL THIOCYANATE(2987-46-4)

Safety Data

• RIDADR: 2811
• HazardClass: 6.1(b)
• PackingGroup: III
• Hazardous Substances Data: 2987-46-4(Hazardous Substances Data)

Usage

General Description

4-Aminophenyl thiocyanate is a chemical compound with the molecular formula C7H6N2S. It is a white crystalline solid that is commonly used in the synthesis of pharmaceuticals and organic compounds. 4-Aminophenyl thiocyanate is a versatile building block in organic chemistry, often utilized as a reagent in the preparation of various chemical compounds. It has a variety of applications, including in the production of dyes, pigments, and pharmaceuticals, as well as in the synthesis of organic compounds for research and industrial use. 4-AMINOPHENYL THIOCYANATE is known for its ability to participate in a range of chemical reactions, making it an important component in organic synthesis.

InChI:InChI=1/C7H6N2S/c8-5-10-7-3-1-6(9)2-4-7/h1-4H,9H2

Upstream product

• 2137-92-0 4-nitrophenyl thiocyanate 
• 60-29-7 diethyl ether 
• 62-53-3 aniline 
• 859214-48-5 2-cyano-4,5-dichloropyridazin-3(2H)-one 
• 1193-02-8 4-aminotiophenol 
• 2290-65-5 trimethylsilyl isothiocyanate 
• 1147550-11-5 ammonium thiocyanate 
• 859214-49-6 2-cyano-4-chloro-5-methoxypyridazin-3(2H)-one 
• 7726-95-6 bromine 
• 64-19-7 acetic acid 
• 7732-18-5 water 
• 67-56-1 methanol 

Downstream Products

• 108480-69-9 methanesulfonic acid-(4-thiocyanato-anilide) 
• 18277-90-2 4-Thiocyanato-azobenzol 
• 50846-16-7 1-Chlor-1-cyano-2-p-thiocyanatophenylethan 
• 7170-77-6 2-amino-6-thiocyanatobenzothiazole 
• 1193-02-8 4-aminotiophenol 
• 637-89-8 4-sulfanylphenol 
• 3321-94-6 N-(4-thiocyanatophenyl)acetamide 
• 104-96-1 4-methylsulfanylaniline 
• 368-77-4 3-trifluoromethylbenzonitrile 
• 874-97-5 3-(hydroxymethyl)benzonitrile 
• 619-72-7 4-nitrobenzonitrile 
• 53078-71-0 4-methoxy-3-methylbenzonitrile 
• 23873-22-5 ethyl N-(4-thiocyanatophenyl)glycinate 
• 40019-45-2 p-methylthiocinnamamidoxime 

Relevant articles and documents

Isoquinolinium-N-sulfonic acid thiocyanate/H2O2 as efficient reagent for thiocyanation of N-bearing (hetero)aromatic compounds

In the present study, isoquinoline sulfonic acid thiocyanate (isoquinoline-SO3H)SCN and isoquinoline sulfonic acid chloride (isoquinoline-SO3H)Cl as a novel and heterogeneous catalyst were designed and synthesized by a simple and ine

A facile synthesis of aryl thiocyanates using sodium perborate

A simple and convenient synthesis of aryl thiocyanates in high yields using sodium perborate is described.

A highly effective green catalyst Ni/Cu bimetallic nanoparticles supported by dendritic ligand for chemoselective oxidation and reduction reaction

The highly active Ni/Cu bimetallic nanoparticles (NPs) of the different molar ratios of Ni and Cu (1:1, 1:3, 3:1) assisted by dendritic ligand 2,4,6-Tris (di-4-chlorobenzamido)-1,3-diazine were synthesized successfully confirmed by Scanning Electron Microscopy (SEM), Electron Diffraction X-ray (EDX), X-ray fluorescence spectroscopy (XRF), X-ray diffraction (XRD), and Transmission Electron Microscopy (TEM) analysis. These NPs were studied as a heterogeneous catalyst for the chemoselective oxidation of alcohol to the corresponding aldehyde at 30?min and chemoselective reduction of aromatic nitro substituents to the corresponding amino substituents at 20?min, while the Ni/Cu (3:1) NPs were found to be the most effective among other Ni/Cu?(1:1)?and Ni/Cu?(1:3)?NPs at room temperature under mild conditions. The Ni/Cu (3:1) NPs can be recycled for at least five successive runs with no perceptible decrease in catalytic activity. Graphic abstract: [Figure not available: see fulltext.]

Porphyrin-Based Conjugated Microporous Polymer Tubes: Template-Free Synthesis and A Photocatalyst for Visible-Light-Driven Thiocyanation of Anilines

Conjugated microporous polymers (CMPs) represent an important type of functional materials. In this area, morphological engineering has remained a major challenge. Here, we report the synthesis of porphyrin-based CMP tubes (CMP-1) through a template-free