71617-15-7Relevant academic research and scientific papers
Hypervalent iodine(III)-mediated decarboxylative acetoxylation at tertiary and benzylic carbon centers
Kiyokawa, Kensuke,Okumatsu, Daichi,Minakata, Satoshi
supporting information, p. 1046 - 1050 (2019/11/11)
The decarboxylative acetoxylation of carboxylic acids using a combination of PhI(OAc)2 and I2 in a CH2Cl2/AcOH mixed solvent is reported. The reaction was successfully applied to two types of carboxylic acids containing an α-quaternary and a benzylic carbon center under mild reaction conditions. The resulting acetates were readily converted into the corresponding alcohols by hydrolysis.
TEMPERATURE DEPENDENCE OF ACTIVATION VOLUME FOR ACETOLYSIS OF 2-ARYL-2-METHYLPROPYL TOSYLATES
Sera, Akira,Yamada, Hiroaki,Masaki, Hitoshi
, p. 1533 - 1536 (2007/10/02)
The activation volume of the acetolysis of the title compounds was found to have an unexpectedly large temperature dependence.The activation volume-temperature profile of a steep concave was observed which was responsible for the previously reported anomaly of the substituent dependence of the activation volume.
