71808-96-3Relevant academic research and scientific papers
Stereoselective Multicomponent Reactions Using Zincate Nucleophiles: β-Dicarbonyl Synthesis and Functionalization
Murphy, Stephen K.,Zeng, Mingshuo,Herzon, Seth B.
, p. 4880 - 4883 (2016)
A general strategy for conjugate addition-C-acylation that enables the synthesis of enantioenriched β-dicarbonyl compounds is described. A novel method for derivatizing these adducts by stereo- and site-selective zinc-catalyzed addition of alkyllithium reagents is also reported. These reactions can be performed in tandem to achieve an enantio- and diastereoselective four-component coupling. The in situ generation of weakly basic lithium zincate species is central to the success of all three transformations.
Synthesis and Photocyclization of 2-Aroyl-3-methylcyclohex-2-enones
Tamura, Yasumitsu,Wada, Akimori,Okuyama, Shigehiro,Fukumori, Satoshi,Hayashi, Yoko,et al.
, p. 1312 - 1320 (2007/10/02)
Preparation and photocyclization of a number of 2-aroyl-3-methylcyclohex-2-enones have been investigated.Irradiation of these systems resulted in a photo-enolization followed by a pericyclic reaction to give 3,4-dihydroanthracen-1(2H)-ones.Keywords - prep
