79482-22-7

Upstream product

• 1193-18-6 3-methylcyclohexen-2-one 
• 98-88-4 benzoyl chloride 
• 344266-54-2 2-benzoyl-3-(di-tert-butyloxycarbonyl)methylcyclohex-2-enone 
• 131223-44-4 1-phenyloct-7-ene-1,3-dione 
• 66049-39-6 3-oxo-1-cyclohexen-1-yl benzoate 
• 504-02-9 1,3-cylohexanedione 
• 1262861-81-3 C₁₄H₁₄O₂ 
• 69629-50-1 2-benzoyl-1,3-cyclohexanedione 
• 79482-32-9 2-benzoyl-3-methyl-2-phenylselenylcyclohexanone 
• 79482-26-1 2-benzoyl-3-chloro-2-cyclohexen-1-one 
• 71808-96-3 2-benzoyl-3-methylcyclohexanone 

Downstream Products

• 81038-97-3 4-methyl-3-phenyl-6,7-dihydro<2,1>benzisoxazole 
• 81039-07-8 2-Benzoyl-3-methyl-cyclohex-2-enone oxime 
• 81039-08-9 2-acetamido-6-methylbenzophenone 
• 345290-94-0 N-Acetyl-N-(2-benzoyl-3-methyl-phenyl)-acetamide 
• 81039-05-6 6,7-dihydro-2,3-diphenyl-4-methyl-2H-indazole 

Relevant academic research and scientific papers

Yb(OTf)3-promoted ZnCl2-catalyzed conia-ene reaction of linear β-alkynic β-dicarbonyls

An atom-economical and solvent-free ytterbium(III) triflate promoted, zinc(II) chloride catalyzed Conia-ene method has been developed for the construction of five- to six-membered-ring carbocycles. In the presence of zinc(II) chloride and ytterbium(III) triflate, a variety of linear β-alkynic β-keto esters and -alkynic -diketones were cyclized under neat conditions in moderate to good yields. It is noteworthy that the selectivity toward five- or six-membered-ring carbocycles depends on substituents at the terminal alkynes. Georg Thieme Verlag Stuttgart.

Palladium-catalyzed intramolecular oxidative alkylation of 4-pentenyl β-dicarbonyl compounds

Reaction of 8-nonene-2,4-dione with a catalytic amount of [PdCl 2(CH3CN)2] (2; 5 mol%) and a stoichiometric amount of CuCl2 (2.5 equiv) at room temperature for 3 h led to oxidative alkylation and formation of 2-

Palladium-catalyzed intramolecular oxidative alkylation of unactivated olefins

Reaction of 5,5-dimethyl-8-nonene-2,4-dione catalyzed by PdCl2(CH3CN)2 (5 mol %) in the presence of CuCl2 (2.5 equiv) at room temperature for 3 h formed 2-acetyl-3,6,6-trimethyl-2-cyclohexenone in 96% isolated yield. Palladium-catalyzed intramolecular oxidative alkylation tolerated a range of substitution and was applicable to the synthesis of spirobicyclic compounds and to the cyclization of ζ-alkenyl β-keto esters. Copyright

Synthesis and Photocyclization of 2-Aroyl-3-methylcyclohex-2-enones

Preparation and photocyclization of a number of 2-aroyl-3-methylcyclohex-2-enones have been investigated.Irradiation of these systems resulted in a photo-enolization followed by a pericyclic reaction to give 3,4-dihydroanthracen-1(2H)-ones.Keywords - prep