71963-96-7

Upstream product

• 592-41-6 1-hexene 
• 1950-78-3 p-toluenesulfonyl iodide 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 7257-26-3 sodium p-toluenesulfinate tetrahydrate 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 105465-39-2 2-(1-pyrrolidinyl)-1-tosylhexane 
• 71964-05-1 (E)-1-(hex-1-en-1-ylsulfonyl)-4-methylbenzene 
• 105235-57-2 (Z)-1-tosyl-1-hexene 
• 188430-23-1 (E)-1-methyl-4-(non-5-en-4-ylsulfonyl)benzene 
• 188430-26-4 (E)-6-propyl-6-tosyl-4-nonene 
• 90633-60-6 1-[((E)-Hex-2-ene)-1-sulfonyl]-4-methyl-benzene 

Relevant academic research and scientific papers

"Syn-Effect" in the Desulfonylation Reaction of α,α-Dialkylated (E)-Allylic Sulfones

It was found that the desulfonylation reaction of α,α-dialkylated (E)-allylic sulfones with a base preferentially affords the sterically unfavorable (Z)-alkadienes. The relative degree of the "syn-effect", which is herein defined as an effect which stabil

Regio- and Stereoselective Synthesis of (E)- and (Z)-Vinylic Sulfones and Their Conversion to the Corresponding Allylic Sulfones

(E)- and (Z)-vinilyc sulfones were prepared regio- and stereoselectively from 1-alkenes or 1-alkynes in high yields via iodosulfonization in AcOEt-H2O.The vinylic sulfones thus prepared were converted to the corresponding allylic sulfones by treatment wit

CONVENIENT METHODS FOR THE PREPARATION OF VINYLIC AND ALLYLIC SULFONES FROM ALKENES

1 or 2-p-Toluenesulfonyl(=tosyl)-1-alkenes were regioselectively prepared from 1-alkenes via iodosulfonization or sulfonylmercuration, respectively.Conversion of 1-tosyl-1-alkenes to the corresponding allylic sulfones, 1-tosyl-2-alkenes, was achieved by t

Copper-Catalyzed Additions of Sulfonyl Iodides to Simple and Cyclic Alkenes

A convenient synthesis for various β-iodo sulfones has been developed.The reaction involves additions of alkane- and arenesulfonyl iodides to simple and cyclic alkenes under the catalytic action of copper(II) chloride.The favored stereochemical results for cyclic alkenes have been rationalized in terms of stepwise addition of both portions of the addend from the diaxial direction.