72087-90-2Relevant academic research and scientific papers
STUDIES OF DITHIIRANES AND THIOSULFINES AS REACTIVE INTERMEDIATES
Senning, Alexander,Hansen, Holger C.,Abdel-Megeed, Mohamed F.,Mazurkiewicz, Witold,Jensen, Birgit
, p. 739 - 746 (1986)
Indirect, but compelling evidence for the intermediacy of dithiiranes 1 and thiosulfines 2 has been found by us and is also provided by literature data.The intriguing dithiirane -> dithioester rearrangement as well as most of the interrelations and conversions postulated in Scheme 1 have been demonstrated experimentally.In a number of cases acetyl α-chloroalkyl disulfides 16 (X=Cl, Y=COCH3) are useful starting materials for the synthesis of thioamides such as 40.
APPROACHES TO THE LIBERATION OF THIOSULFINES
Franek, Walter
, p. 381 - 382 (2007/10/02)
In 1979 A.Senning found a series of reactions that involve probably thiosulfines of thiocarbonyl S-sulfides.Now, disulfide 5a was chosen for a re-examination, as no rearrangements seem to be involved.F, Cl, Br, CH3, and CH3O are used to change the electro
SCHWEFELHALTIGE DERIVATIVE DES DIBENZOYLMETHANS.
Senning, Alexander
, p. 323 - 326 (2007/10/02)
A number of sulfur-containing derivatives of dibenzoylmethane were obtained by conversions involving the active methylene group.
