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72151-34-9

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72151-34-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 72151-34-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,2,1,5 and 1 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 72151-34:
(7*7)+(6*2)+(5*1)+(4*5)+(3*1)+(2*3)+(1*4)=99
99 % 10 = 9
So 72151-34-9 is a valid CAS Registry Number.

72151-34-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name dichloroplatinum(2+),2-methylpiperidin-1-ide

1.2 Other means of identification

Product number -
Other names trans-Pt(2-methylpyridine)2Cl2

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:72151-34-9 SDS

72151-34-9Relevant articles and documents

Synthesis and NMR characterization of the novel mixed-ligand Pt(II) complexes cis- and trans-Pt(Ypy)(pyrimidine)Cl2 and trans,trans-Cl2(Ypy)Pt(μ-pyrimidine)Pt(Ypy)Cl2 (Ypy = pyridine derivative)

Rochon, Fernande D.,Fakhfakh, Majd

, p. 1455 - 1466 (2009/08/08)

Mixed-ligand complexes of the type cis- and trans-Pt(Ypy)(pm)Cl2 where Ypy = pyridine derivative and pm = pyrimidine were synthesized and characterized by IR spectroscopy and by multinuclear (195Pt, 1H and 13C) magnetic resonance spectroscopy. The cis compounds were prepared from the reaction of K[Pt(Ypy)Cl3] with pyrimidine (1:1 proportion) in water, while most of the trans isomers were synthesized from the isomerization of the cis compounds. The cis isomers could not be isolated with the Ypy ligands containing two -CH3 groups in ortho positions. When the aqueous reaction of K[Pt(Ypy)Cl3] with pyrimidine was performed in a Pt:pm ratio = 2:1, the pyrimidine-bridged dinuclear species were formed. Only the most stable trans-trans isomers could be isolated pure. In IR spectroscopy, the cis monomers showed two ν(Pt-Cl) bands, while the trans monomers and dimers showed only one ν(Pt-Cl) band. The 195Pt NMR signals of the cis monomers were found at slightly higher fields than those of the corresponding trans isomers. The δ(195Pt) of the dimers were found close to those of the trans monomers. The NMR results were interpreted in relation to the solvent effect, which seems important in these complexes. The coupling constants J(195Pt-1H) and J(195Pt-13C) are larger in the cis geometry. The crystal structures of the compounds cis-Pt(2,4-lut)(pm)Cl2, trans-Pt(2,6-lut)(pm)Cl2 and trans,trans-Cl2(2,6-lut)Pt(μ-pm)Pt(Ypy)Cl2 were studied by X-ray diffraction methods and the results have confirmed the configurations suggested by IR and NMR spectroscopies.

The cis- and trans-Effects of Cyanide in Substitution at Platinum(II)

Cattalini, Lucio,Guidi, Francesca,Tobe, Martin L.

, p. 233 - 236 (2007/10/02)

The cis- and trans- isomers (am = dimethylamine, pyridine, 4-cyanopyridine, 4-chloropyridine, 2-methylpyridine, 4-methylpyridine, 2,4-dimethylpyridine, 4-ethylpyridine, morpholine or piperidine), react rapidly with excess CN(1-) in methanol to

Nucleophilic displacement of the chelating bis(sulfoxide) from cis-[meso-1,2-bis(phenylsulfinyl)ethane]dichloroplatinum(II) and cis-[rac-1,2-bis(phenylsulfinyl)ethane]dichloroplatinum(II)

Cattalini, Lucio,Marangoni, Giampaolo,Michelon, Gianni,Paolucci, Gino,Tobe, Martin L.

, p. 71 - 75 (2008/10/08)

The kinetics of ring opening, by amines in 1,2-dimethoxyethane, have been measured for two bis(sulfoxide)-platinum(II) isomers. The results make possible a discussion of the differences between the two isomers, in comparison with other platinum(II) complexes, in terms of absolute reactivity, nucleophilic discrimination, and steric retardation effects.

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