72454-22-9Relevant academic research and scientific papers
The Germanium-Carbon Bond Cleavage Reaction of (Germylmethyl)amine Derivatives. Mechanism and Stereochemistry
Terunuma, Daiyo,Masuo, Koujiro,Kizaki, Hiroaki,Nohira, Hiroyuki
, p. 160 - 164 (2007/10/02)
A facile cleavage reaction of the germanium-carbon bond of (germylmethyl)amine derivatives to give a germyl anion and an azomethine derivative was developed.The effects of substituents such as phenyl, benzyl, and ethyl groups on the germanium and nitrogen atoms of the (germylmethyl)amine derivatives on the cleavage reaction were investigated.The mechanism was also investigated based on the stereochemistry of the cleavage reaction using an optically active organogermanium compound.
Facile Cleavage of Ge-C Bonds of N-(Germylmethyl)benzylamine Derivatives. Generation of Germyl Anions
Terunuma, Daiyo,Kizaki, Hiroaki,Sato, Takashi,Masuo, Koujiro,Nohira, Hiroyuki
, p. 97 - 100 (2007/10/02)
The reactions of N-(germylmethyl)benzylamine derivatives with butyllithium were carried out.Facile cleavages of Ge-C bonds of the N-benzylgermylmethylamine derivatives giving the corresponding germyl anions and N-pentylbenzylamine were observed.The reacti
Preparation and Some Reactions of Diarylgermylenedialkali Metals
Mochida, Kunio,Matsushige, Naoki,Hamashima, Mari
, p. 1443 - 1447 (2007/10/02)
The reactions of diarylgermanes with alkali metals in HMPA/THF or THF were found to give the corresponding diarylgermylenedialkali metals in high yields.Diphenylgermylenedipotassium reacted with aryl halides or carbonyl compounds to give reduction products predominantly.With alkyl halides, diphenylgermylenedipotassium gave mainly substitution products.
