728039-63-2

Usage

Uses

Used in Pharmaceutical Industry:
Bisbiphenyl-4-yl-(4'-bromo-biphenyl-4-yl)-amine is used as a key intermediate in the synthesis of pharmaceutical compounds due to its diverse reactivity and functionality. Its unique structure allows for the development of new drugs with potential therapeutic applications.
Used in Agrochemical Industry:
In the agrochemical field, Bisbiphenyl-4-yl-(4'-bromo-biphenyl-4-yl)-amine serves as a crucial component in the creation of novel agrochemicals. Its properties enable the design of effective pesticides and other agricultural chemicals that can improve crop protection and yield.
Used in Material Sciences:
Bisbiphenyl-4-yl-(4'-bromo-biphenyl-4-yl)-amine is utilized as a building block in the development of advanced materials with specific properties. Its versatility in chemical reactions allows for the synthesis of materials with applications in various industries, such as electronics, coatings, and plastics.
Used in Research Applications:
As a chemical compound with unique properties, Bisbiphenyl-4-yl-(4'-bromo-biphenyl-4-yl)-amine is extensively used in research for exploring its potential applications and understanding its chemical behavior. It serves as a valuable tool for scientists to investigate new reactions and develop innovative synthetic routes.

Synthetic route

4-bromo-4'-iodobiphenyl (105946-82-5) + bis(biphenyl-4-yl)amine (102113-98-4) → N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2)

Conditions	Yield
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene for 2h; Reflux;	90%
With palladium diacetate; triphenylphosphine; sodium t-butanolate In toluene at 80℃; for 8h; Inert atmosphere;	83%
With copper(l) iodide; 1,10-Phenanthroline; potassium tert-butylate In toluene at 100℃; for 48h; Inert atmosphere;	82%

4-(4-bromophenyl)bromobenzene (92-86-4) + bis(biphenyl-4-yl)amine (102113-98-4) → N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2)

Conditions	Yield
With palladium diacetate; triphenylphosphine; sodium t-butanolate In toluene Inert atmosphere; Reflux;	78%
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene for 2h; Reflux;	75%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium t-butanolate In toluene at 80℃; for 25h; Inert atmosphere;	74%

N,N-di-(4-biphenyl)benzylamine (462631-32-9) + palladium-active carbon + palladium (7440-05-3) → N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + bis(biphenyl-4-yl)amine (102113-98-4)

Conditions	Yield
With hydrogen In ethanol; dichloromethane; chloroform; toluene

bis(triphenylphosphine)palladium(II) dichloride + 4-(4-bromophenyl)bromobenzene (92-86-4) + bis(biphenyl-4-yl)amine (102113-98-4) → N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2)

Conditions	Yield
In 5,5-dimethyl-1,3-cyclohexadiene; water; toluene
In 5,5-dimethyl-1,3-cyclohexadiene; water
In 5,5-dimethyl-1,3-cyclohexadiene; water; toluene

→ N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2)

Conditions	Yield
Multi-step reaction with 3 steps 1.1: sodium t-butanolate; palladium diacetate; tri-tert-butyl phosphine / toluene / 7 h / 20 - 120 °C / Inert atmosphere 1.2: 12 h / Inert atmosphere 2.1: palladium 10% on activated carbon; hydrogen / chloroform; ethanol / 0.5 h / 20 °C 3.1: sodium t-butanolate; bis-triphenylphosphine-palladium(II) chloride / 5,5-dimethyl-1,3-cyclohexadiene / 24 h / 130 °C / Inert atmosphere View Scheme
Multi-step reaction with 2 steps 1: tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate / 3 h / 90 °C 2: tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate / toluene / 3 h / 90 °C View Scheme
Multi-step reaction with 2 steps 1: sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene / 24 h / 100 °C 2: 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; palladium diacetate; sodium t-butanolate / toluene / 24 h / 100 °C View Scheme

4,4'-diiodobiphenyl (3001-15-8) + bis(biphenyl-4-yl)amine (102113-98-4) → N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2)

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene at 130℃; for 24h; Inert atmosphere;	9.1 g

N,N-di-(4-biphenyl)benzylamine (462631-32-9) → N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2)

Conditions	Yield
Multi-step reaction with 2 steps 1: palladium 10% on activated carbon; hydrogen / chloroform; ethanol / 0.5 h / 20 °C 2: sodium t-butanolate; bis-triphenylphosphine-palladium(II) chloride / 5,5-dimethyl-1,3-cyclohexadiene / 24 h / 130 °C / Inert atmosphere View Scheme

4-Aminobiphenyl (92-67-1) → N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2)

Conditions	Yield
Multi-step reaction with 2 steps 1: tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate / 3 h / 90 °C 2: tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate / toluene / 3 h / 90 °C View Scheme
Multi-step reaction with 2 steps 1: sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene / 24 h / 100 °C 2: 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; palladium diacetate; sodium t-butanolate / toluene / 24 h / 100 °C View Scheme

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) → C60H42N2O2

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 100℃; for 46h;	100%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + bis(pinacol)diborane (73183-34-3) → N,N-bis({[1,1'-biphenyl]-4-yl})-4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-4-amine (1421701-43-0)

Conditions	Yield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane at 100℃; for 12h; Inert atmosphere;	98%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In toluene Reflux;	84%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In toluene Reflux;	84%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In toluene Reflux;	84%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In 1,4-dioxane at 80℃; Inert atmosphere;	77%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + C43H51NO4 → C79H76N2O4

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; hexane at 100℃; for 2h; Inert atmosphere;	92%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + C28H18BrN → C64H43BrN2

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 110℃; for 17h; Inert atmosphere;	91%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + N-phenyl-1-triphenylenylamine → C60H42N2

Conditions	Yield
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In o-xylene at 140℃; for 24h; Inert atmosphere;	90%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + bis(biphenyl-4-yl)amine (102113-98-4) → N,N,N',N'-tetra[(1,1'-biphenyl)-4-yl]-(1,1'-biphenyl)-4,4'-diamine

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 100℃; for 24h;	80%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + N-[1,1′-biphenyl]-3-yl[1,1′-biphenyl]-3-amine → C60H44N2

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 100℃; for 24h;	79%

3-aminodibenzofuran (4106-66-5) + N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) → C48H34N2O

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 90℃; for 5h; Inert atmosphere;	78.42%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + N-([1,1′-biphenyl]-4-yl)-[1,1′:4′,1″-terphenyl]-4-amine (897921-63-0) → C66H48N2

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 8h; Inert atmosphere; Reflux;	77%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 8h; Reflux;	77%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + 2-{bis(biphenyl-4-yl)amino}phenylboronic acid → 2,4''-bis{bis(biphenyl-4-yl)amino}-1,1':4',1"-terphenyl

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 20h; Inert atmosphere; Reflux;	76%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + 9-((4-diphenylamino)phenyl)-9H-carbazol-2-yl-2-boronic acid → bis-biphenyl-4-yl-{4'-[9-(4-diphenylaminophenyl)-9H-carbazol-2-yl]biphenyl-4-yl}amine

Conditions	Yield
With palladium diacetate; potassium carbonate In tetrahydrofuran; water at 60℃; for 12h; Inert atmosphere;	75%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + N-phenyl-[1,1':4',1"-terphenyl]-4-amine (897671-81-7) → C60H44N2

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 8h; Inert atmosphere; Reflux;	75%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 8h; Reflux;	75%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + C33H22N2O → C69H47N3O

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 6h; Inert atmosphere; Reflux;	75%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + 5,5-Dimethyl-5,10-dihydro-benzo<1,8>naphthyridin (90903-64-3) → N,N-di([1,1'-biphenyl]-4-yl)-4'-(5,5-dimethylbenzo[b][1,8]naphthyridine-10(5H)-yl)-[1,1'-biphenyl]-4-amine

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; potassium tert-butylate In o-xylene at 120℃; for 12h; Inert atmosphere;	72%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + (9,9-dimethyl-9H-fluoren-3-yl)phenylamine → C57H44N2

Conditions	Yield
Stage #1: N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine; (9,9-dimethyl-9H-fluoren-3-yl)phenylamine for 1h; Inert atmosphere; Stage #2: With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate for 18h; Inert atmosphere; Reflux;	71%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + N-([1,1‘-biphenyl]-4-yl)-[1,1‘-biphenyl]-2-amine (1372775-52-4) → C60H44N2 (1608462-65-2)

Conditions	Yield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene Inert atmosphere; Reflux;	70%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + N-(dibenzofuran-2-yl)-N-phenyl-amine (861317-95-5) → C54H38N2O (1318338-56-5)

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 80℃; for 2h; Inert atmosphere;	70%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + 10-phenyl-3,10-dihydropyrrolo[3,2-a]carbazole → C56H39N3

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate In water; toluene at 100℃; for 24h;	68%

N-[1,1'-biphenyl]-4-yl-N-(4'-bromo[1,1'-biphenyl]-4-yl)-[1,1'-biphenyl]-4-amine (728039-63-2) + 10H-benzofuro[3,2-b]indole (248-66-8) → C50H34N2O

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate In toluene at 100℃; for 24h;	66%
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate In toluene at 100℃; for 24h;	66%

Upstream product

• 462631-32-9 N,N-di-(4-biphenyl)benzylamine 
• 7440-05-3 palladium 
• 92-86-4 4-(4-bromophenyl)bromobenzene 
• 102113-98-4 bis(biphenyl-4-yl)amine 
• 92-67-1 4-phenylalanine 
• 3001-15-8 4,4'-diiodobiphenyl 
• 92-66-0 4-bromo-1,1'-biphenyl 
• 105946-82-5 4-bromo-4'-iodobiphenyl 

Downstream Products

• 1007387-52-1 C₆₄H₄₆N₂S 
• 1421701-39-4 C₅₄H₃₆N₂ 
• 1421701-44-1 C₆₀H₄₀N₂ 
• 1421701-43-0 N,N-bis({[1,1'-biphenyl]-4-yl})-4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-4-amine 

Relevant academic research and scientific papers

Effect of arylamino-carbazole containing hole transport materials on the device performance and lifetime of OLED

We synthesized four hyper-conjugated aromatic hole transporting materials with different molecular geometry and energy levels by attaching arylamino moiety attached to the carbazole core. A brominated carbazole moiety reacted with an arylamino moiety using a Buchwald-Hartwig reaction. The characteristics of these hole transporting materials were investigated using TGA, DSC, UV–Vis and luminescence spectroscopy. The energy levels of all materials used in this study were estimated from cyclic voltammograms and absorption spectra. The hole transporting properties of the synthesized molecules were measured using single-carrier devices. All four hole transporting materials showed similar hole mobility. The effectiveness of hole transporting materials was compared by fabricating green-emitting organic light emitting diode (OLED) devices. It turned out that the device performances were critically dependent on the relative energy levels of the hole transporting layer and emission layer. However, the molecular geometry greatly influenced the device lifetime, determining thermally induced crystallization by the heat produced during device operation.

Aromatic amine compound containing carbazole group and organic light emitting diode thereof

The invention discloses an aromatic amine compound containing a carbazole group and an organic light emitting diode thereof, and relates to the technical field of organic photoelectric materials. Thearomatic amine compound structurally contains the specific carbazole group, on one hand, the carbazole group has a high triplet state energy level and a high hole mobility, on the other hand, the carbazole group has a relatively high redox potential value and has good stability under the condition of air or illumination, in addition, four hydrogen bonds of a phenyl group on a N site of the substituted carbazole group are replaced by four deuterium bonds, deuterium is non-toxic and non-radioactive and is 6-9 times more stable than a carbon-hydrogen bond, and therefore the compound with more stable property is obtained; in addition, by means of the carbazole and ortho-position connected biphenyl, conjugating of the structure is extended, and the hole transmission is facilitated; and the obtained aromatic amine compound is used as a hole-transport material or an optical extraction layer material in the organic light emitting diode and has the advantages of being high in efficiency, high in brightness and long in service life.

Triarylamine derivative, preparation method, application and device thereof

Belonging to the technical field of photoelectric material applied science and technology, the invention in particular relates to a triarylamine derivative, a preparation method and application thereof. The triarylamine derivative provided by the invention adopts triarylamine and fluorenocarbazole as the basic structural unit, and after modification, an asymmetric structure can be obtained so as to compose compounds rich in holes and with high glass transition temperature. When the compounds are used as a hole transport material, compared with the commonly used hole transport material like N,N'-diphenyl-N, N'-bis(3-methylphenyl)-1, 1'-biphenyl-4, 4'-diamine (TPD) in the prior art, the hole transport ability is significantly improved, in OLEDs, the series of compounds have significantly improved starting voltage and glass transition temperature compared with the traditional hole transport materials, and are ideal hole transport materials. In addition, when the series of compounds are used as a light-emitting layer, the efficiency of OLEDs is greatly improved, and the series of compounds are ideal light-emitting layer materials.

COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND A ELECTRONIC DEVICE THEREOF

The present invention relates to a compound for an organic electronic element, an organic electronic element using the same, and an electronic device thereof and, more specifically, to a novel compound comprising O atom heterocycles capable of improving luminous efficiency, stability, and service life of an element, an organic electronic element using the same, and an electronic device thereof.

Nitrogenous heterocyclic ring derivative and organic light emitting device thereof

The invention provides a nitrogenous heterocyclic ring derivative and an organic light emitting device thereof, and relates to the technical field of organic photoelectric materials. On one hand, acridine is a macrocyclic conjugated system with a rigid plane structure, the rigid molecular skeleton of the macrocyclic conjugated system is favorable for improving the light and heat stability and thefluorescence quantum efficiency of the material, and meanwhile, the larger pi conjugated system can be used for improving the carrier injection and transmission property of the module. On the other hand, an acridine ring structure and a biphenyl structure generally form a p-pi large conjugation state through a nitrogen atom link, a large conjugate ring electron containing ability is enhanced, thenitrogen atom has a higher electron giving ability, a cavity can be more easily subjected to oxidation formation to display positive electricity, and therefore, the nitrogenous heterocyclic ring derivative has a high cavity migration rate. The organic light emitting device prepared by taking the structure as a cavity transmission material has the advantages of high light emitting efficiency and low driving voltage.

Heterocyclic compounds and organic electroluminescence devices thereof

The invention provides heterocyclic compounds and organic electroluminescence devices thereof, and belongs to the technical field of organic electroluminescence materials. Amine type groups are introduced to specific positions of a naphthalene ring, thus properly adjusting the hole mobility and achieving an objective of balancing the hole mobility and carrier mobility. An exciton composition zoneis completely in a luminescence layer. A triarylamine structure is connected to an amine group on one side of the heterocyclic compounds to increase hole transporting capability. In addition, a carbonatom is provided with two substitute groups, making structures of the compounds similar to the structure of spirofluorene, thus ensuring that the compounds have higher glass transition temperatures.A technical problem that organic electroluminescence materials in the prior art have poor luminescence properties such as low luminescence efficiency and short service lifetime is solved. Compared with the prior art, the organic electroluminescence devices based on organic electroluminescence materials and ink compositions have improved luminescence properties and the compounds are excellent OLEDmaterials.

A heterocyclic compound and its organic light-emitting device (by machine translation)

The present invention provides a heterocyclic compound and its organic light-emitting device, which belongs to the technical field of organic photoelectric material. In particular in the specific position of the naphthalene ring is introduced on the amide group, thus can be appropriate adjusting hole mobility, reach the hole mobility and balance the purpose of carrier mobility. The exciton consistent with the regional totally in the luminescent layer. Heterocyclic compounds at one side of the amide group on the amine structure connected, increase its hole transmission ability. At the same time a relatively large molecule volume and molecular weight it ensures that this material has higher glass transition temperature. In the prior art can be effectively solve the organic photoelectric material luminous efficiency is low, the driving voltage is relatively high, and short service life of the technical problem of poor performance of the. Compared with the prior art, the invention is based on organic electroluminescent material and ink composition of the organic light-emitting device, can significantly improve the luminescence, is an excellent OLED material. (by machine translation)

Arylamine-based compound and organic light emitting diode comprising the same

An arylamine-based compound is represented by Formula 1 below. The arylamine-based compound is included in an organic light emitting diode.

ORGANIC COMPOUND AND ORGANIC LIGHT EMITTING DIODE AND ORGANIC LIGHT EMITTING DIODE DISPLAY DEVICE USING THE SAME

The present invention relates to an organic compound in which two amine groups are connected by biphenylene, and one or two substituents having a silyl group is or are connected to nitrogen atoms forming the amine groups. According to the present invention, the organic compound is excellent in hole injection properties, hole transport properties and/or electron blocking properties by comprising the amine groups. Further, the organic compound has improved light emitting efficiency compared to the case in which the substituent which does not have the silyl group, or has two or more silyl groups is connected to the nitrogen atoms. Therefore, when the organic compound of the present invention is applied to a hole layer, an electron blocking layer and/or a charge generation layer of an organic light emitting diode, light emitting efficiency is improved, and current density can be reduced. Accordingly, light emitting efficiency of the organic light emitting diode, to which the organic compound of the present invention is applied, can be greatly improved.COPYRIGHT KIPO 2018

Arylamine derivative and organic electroluminescent device thereof

The invention provides an arylamine derivative and an organic electroluminescent device thereof and relates to the technical field of organic photoelectric materials. The arylamine derivative has theadvantages of simple preparation method, easily obtained raw materials, very good stability, very good film-forming property and good hole transporting ability; and meanwhile, the arylamine derivativehas an appropriate highest occupied molecular orbital energy level (HOMO) and a first triplet energy level (T1) value and can be applied to the OLED device as a luminescence assisting layer to realize balance of charges in a luminescent layer and prevent exciton from diffusing to one side of a hole transporting layer. Therefore, the arylamine derivative provided by the invention is applied to theOLED device as the hole transporting layer and the luminescence assisting layer and has the advantages that the luminescence efficiency of the device can be obviously enhanced, the color purity of the device can be obviously enhanced, the service life of the device can be effectively prolonged, the driving voltage of the device can also be effectively reduced, and the arylamine derivative is an OLED material with excellent performance.