73010-54-5Relevant academic research and scientific papers
Direct synthesis of anilines and nitrosobenzenes from phenols
St Amant,Frazier,Newmeyer,Fruehauf,Read De Alaniz
, p. 5520 - 5524 (2016/07/06)
A one-pot synthesis of anilines and nitrosobenzenes from phenols has been developed using an ipso-oxidative aromatic substitution (iSOAr) process. The products are obtained in good yields under mild and metal-free conditions. The leaving group effect on reactions that proceed through mixed quionone monoketals has also been investigated and a predictive model has been established.
Mixed quinone monoketals via iodobenzene diacetate oxidation
Fleck,Hobart,Morrow
, p. 179 - 187 (2007/10/02)
Oxidation of p-methoxyphenol, 4-methoxynaphthol and 4-acetamidophenol with iodobenzenediacetate in various alcohols as solvent afforded the corresponding mixed quinone or naphthoquinone monoketals in good yield. Oxidation of p-methoxyphenol in the presenc
