73013-51-1

Usage

Uses

Since the specific applications or uses of 4-(2-Oxo-Propyl)-Benzoic Acid Ethyl Ester are not readily available, it is likely used primarily for scientific research or as a byproduct or intermediate in the synthesis of other compounds in various chemical reactions. However, based on its chemical structure and the general properties of benzoic acid esters, it can be inferred that it may have potential applications in the following areas:
Used in Chemical Synthesis:
4-(2-Oxo-Propyl)-Benzoic Acid Ethyl Ester is used as an intermediate or byproduct in the synthesis of other organic compounds for various applications, such as pharmaceuticals, agrochemicals, or specialty chemicals.
Used in Scientific Research:
4-(2-Oxo-Propyl)-Benzoic Acid Ethyl Ester is used as a research compound to study its chemical properties, reactivity, and potential applications in various fields, including material science, catalysis, or organic synthesis.

InChI:InChI=1/C12H14O3/c1-3-15-12(14)11-6-4-10(5-7-11)8-9(2)13/h4-7H,3,8H2,1-2H3

Upstream product

• 3002-24-2 hexane-2,4-dione 
• 51934-41-9 4-iodobenzoic acid ethyl ester 
• 123-54-6 acetylacetone 
• 1139705-24-0 4-(imidazole-1-sulfonyloxy)-benzoic acid ethyl ester 
• 67-64-1 acetone 
• 108-22-5 Isopropenyl acetate 
• 348-06-1 p-carboethoxybenzenediazonium tetrafluoroborate 
• 94-09-7 p-aminoethylbenzoate 
• 116-11-0 2-Methoxypropene 

Downstream Products

• 1333377-91-5 ethyl 4-(1,4-dioxo-1,2-diphenylpentan-3-yl)benzoate 
• 1220904-23-3 ethyl 4-(2-hydroxypropyl)benzoate 

Relevant academic research and scientific papers

Photoinduced Cross-Coupling of Aryl Iodides with Alkenes

A protocol for photoinduced cross-coupling of aryl iodides having polar π-functional groups or elongated π-conjugation with alkenes has been developed. The radical cascade mechanism involving generation of aryl radicals via C-I bond homolysis of photoexcited aryl iodides and their subsequent addition to alkenes is proposed. The method enables iodide-selective cross-coupling over other halogen leaving groups with functional group compatibility on both arene and alkene motifs.

UiO-66 microcrystals catalyzed direct arylation of enol acetates and heteroarenes with aryl diazonium salts in water

UiO-66 is a classic Metal–organic framework (MOF) that constructed by zirconium cations and terephthalate with high chemical and thermal stability. Using pristine UiO-66 nanocrystals as the catalysts, the carbon–carbon bond formation based on denitrogenat

C-H arylation reactions through aniline activation catalysed by a PANI-g-C3N4-TiO2 composite under visible light in aqueous medium

A PANI (polyaniline)-g-C3N4-TiO2 composite was prepared and found to be efficient for radical C-H arylation reactions. The arylation process involved coupling of in situ generated aryl diazonium salts from aniline with heteroarenes, enol acetates or benzoquinones under visible light in aqueous medium or pure water. A broad range of substrates survived the reaction conditions to provide the desired products in moderate to good yields. Scale-up (10 mmol) synthesis was also achieved. This semiconductor photocatalyst showed good photocatalytic performance and stability. Recycle studies showed that this composite could be readily recovered and a slight decrease in the catalytic activity was observed after ten consecutive runs.

Visible-light-mediated α-arylation of enol acetates using aryl diazonium salts

Visible light mediates efficiently the α-arylation of enol acetates by aryl diazonium salts under mild conditions using [Ru(bpy)3]Cl 2 as a photoredox catalyst. The broad scope of the reaction toward various diazonium salts and enol acetates was explored. The application of this reaction in the concise synthesis of 2-substituted indoles was demonstrated

Palladium-catalyzed mono-α-arylation of acetone with aryl imidazolylsulfonates

Set the ace(tone): A palladium catalyst derived from the bidentate XantPhos ligand and Pd(OAc)2 has enabled broadly applicable mono-α-arylations of acetone to be performed with air- and moisture-stable aryl imidazolylsulfonates as most user-friendly electrophiles (see scheme). Copyright

Copper catalyzed arylation/C-C bond activation: An approach toward α-aryl ketones

An efficient arylation/C-C activation process was discovered. -Diketones with aryl halides (aryl iodides and aryl bromides) could undergo reaction smoothly in the presence of Cu(I) or Cu(II) salts in DMSO using K3 PO4 3H2 O without ligands. The role of H2 O was unprecedented, which assisted the C-C activation. Various -aryl ketones could be efficiently synthesized by this novel method. In situ monitoring of the formation of KOAc and experimentation relating to "a classic diagnostic technique for the participation of radical anion intermediates" revealed the preliminary mechanistic information for the reaction. This method is simple, general, and practical which complemented the classic method for the rapid construction of C-C bonds to a carbonyl moiety.