7306-12-9

Basic information

• Product Name: ACETIC ACID 3-PHENYL-BUT-3-ENYL ESTER
• Synonyms: Benzenepropanol,.gamma.-methylene-,acetate;gamma-methylene-benzenepropanoacetate;3-PHENYL-3-BUTEN-1-YL ACETATE;ACETIC ACID 3-PHENYL-BUT-3-ENYL ESTER;ANISIMAL;2-Phenyl-4-acetoxy-1-butene;3-Phenyl-3-butenyl=acetate;Acetic acid 3-phenyl-3-butenyl ester
• CAS NO: 7306-12-9
• Molecular Formula: C₁₂H₁₄O₂
• Molecular Weight: 190.24
• EINECS: 230-755-3
• Product Categories: pharmacetical
• Mol File: 7306-12-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 287.9°Cat760mmHg
• Flash Point: 125°C
• Appearance: /
• Density: 1.01g/cm³
• Vapor Pressure: 0.00242mmHg at 25°C
• Refractive Index: 1.508
• CAS DataBase Reference: ACETIC ACID 3-PHENYL-BUT-3-ENYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: ACETIC ACID 3-PHENYL-BUT-3-ENYL ESTER(7306-12-9)
• EPA Substance Registry System: ACETIC ACID 3-PHENYL-BUT-3-ENYL ESTER(7306-12-9)

Safety Data

• Hazardous Substances Data: 7306-12-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H14O2/c1-10(8-9-14-11(2)13)12-6-4-3-5-7-12/h3-7H,1,8-9H2,2H3

Upstream product

• 7133-68-8 3-phenylbutane-1,3-diol 
• 127-09-3 sodium acetate 
• 108-24-7 acetic anhydride 
• 50-00-0 formaldehyd 
• 98-83-9 isopropenylbenzene 
• 77-83-8 fraeseol 
• 84736-61-8 (+/-)-(3-hydroxy-3-phenyl-butyl)-acetate 
• 1200-73-3 4-methyl-4-phenyl-1,3-dioxane 
• 141-78-6 ethyl acetate 
• 64-19-7 acetic acid 

Downstream Products

• 69096-86-2 2-(1-phenylcyclopropyl)ethyl acetate 
• 39146-08-2 2,3,4,5-tetrahydrobiphenyl-3,4-dicarboxylic acid 
• 103987-48-0 3-Phenyl-buten-⁽³⁾-yl-formiat 
• 5747-05-7 (4-chlorobut-1-en-2-yl)benzene 
• 2722-36-3 3-phenyl-1-butanol 
• 10107-60-5 1,4-diphenyl-4-vinylcyclohex-1-ene 
• 92-92-2 biphenyl-4-carboxylic acid 
• 807349-45-7 4-phenyl-cyclohex-3-enecarbaldehyde 
• 150131-89-8 3-phenyl-3-cyclohexenecarboxylic acid 
• 61414-85-5 4-phenylcyclohex-3-ene-1-carboxylic acid 
• 6337-27-5 (+/-)-4-phenyl-cyclohex-4-ene-1r,2c-dicarboxylic acid-anhydride 
• 100993-70-2 3-phenyl-3-oxopropyl N,N,N'-tris(2-chloroethyl)phosphorodiamidate 
• 100993-67-7 3-phenyl-3-butenyl N,N,N'-tris(2-chloroethyl)phosphorodiamidate 
• 100993-69-9 3-phenyl-3-oxopropyl N,N'-bis(2-chloroethyl)phosphorodiamidate 

Relevant articles and documents

Stereoselective reductions of N-Boc-hexahydro-1H-indolin-5(6H)-ones

We report the divergent effects of a 3a-methyl and 3a-phenyl substituent on the chemoselectivity and stereoselectivity of reduction of the enamide moiety of N-Boc-hexahydro-1H-indolin-5(6H)-ones. Under ionic reduction conditions (triethylsilane/trifluoroacetic acid) the enamide group of 3a-methyl-N-Boc-hexahydro-1H-indolin-5(6H)-one was reduced to afford exclusively a cis ring-fused product. For the 3a-phenyl substituted analogue more forcing conditions (sodium cyanoborohydride at pH 2-2.5) were required and resulted in the selective reduction of the enamide group to give a trans ring-fused product as well as reduction of the ketone group.

REACTION OF 4- AND 4,4-SUBSTITUTED 1,3-DIOXANES WITH ETHYL ACETATE

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