730970-91-9

Basic information

• Product Name: N-methyl-N-(2-nitro-benzoyl)-anthranilic acid methyl ester
• CAS NO: 730970-91-9
• Molecular Weight: 314.298
• Mol File: 730970-91-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-methyl-N-(2-nitro-benzoyl)-anthranilic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl-N-(2-nitro-benzoyl)-anthranilic acid methyl ester(730970-91-9)
• EPA Substance Registry System: N-methyl-N-(2-nitro-benzoyl)-anthranilic acid methyl ester(730970-91-9)

Safety Data

• Hazardous Substances Data: 730970-91-9(Hazardous Substances Data)

Upstream product

• 552-16-9 ortho-nitrobenzoic acid 
• 610-14-0 2-nitrobenzyl chloride 
• 74-83-9 methyl bromide 
• 72367-10-3 2-(2-nitrobenzoylamino)benzoic acid methyl ester 
• 119-68-6 N-Methylanthranilic acid 
• 85-91-6 Methyl N-methylanthranilate 

Downstream Products

• 1616495-21-6 methyl 2-(2-acetamido-N-methylbenzamido)benzoate 
• 83432-92-2 N-methyl-N-(o-nitrobenzoyl)anthranilic acid 
• 54083-72-6 methyl N-methyl-N-(o-aminobenzoyl)anthranilate 

Relevant articles and documents

Intramolecular metal-free oxidative aryl-aryl coupling: An unusual hypervalent-iodine-mediated rearrangement of 2-substituted n-phenylbenzamides

Hypervalent-iodine-mediated oxidative coupling of the two aryl groups in either 2-acylamino-N-phenyl-benzamides or 2-hydroxy-N-phenylbenzamides, with concomitant insertion of the ortho-substituted N or O atom into the tether, has been described for the first time. This unusual metal-free rearrangement reaction involves an oxidative C(sp2)?C(sp2) aryl-aryl bond formation, cleavage of a C(sp2)?C(O) bond, and a lactamization/lactonization. Furthermore, unsymmetrical diaryl compounds can be easily obtained by removing the tether within the cyclized product.