73120-08-8Relevant academic research and scientific papers
Solvolysis of trimethylsilyl-N-aryl carbamates
Boecskei, Zsolt,Knausz, Dezsoe,Gal, Miklos,Szakacs, Laszlo,Csakvari Bela
, p. 159 - 166 (2007/10/02)
The kinetics of the solvolysis reaction of various trimethylsilyl esters of N-aryl carbamic acid with isopropanol was studied.UV spectrophotometry was used to monitor the reaction and the pseudo first order rate constants were determined.The experiments w
TRIMETHYLSILYLATED N-ARYL-SUBSTITUTED CARBAMATES
Knausz, Dezsoe,Kolos, Zsuzsa,Rohonczy, Janos,Ujszaszy, Kalman
, p. 167 - 170 (2007/10/02)
Trimethylsilyl N-aryl carbamates were prepared by reaction of the respective aniline derivatives, hexamethyldisilazane and carbon dioxide.Two mol-percent of anhydrous CoCl2 was found to act as a catalyst permitting to double the yield during an equal reaction time.
