73198-78-4

Basic information

• Product Name: 2-TRIMETHYLSILYL-N-TERT-BUTYLACETALDIMINE
• Synonyms: 2-TRIMETHYLSILYL-N-TERT-BUTYLACETALDIMINE
• CAS NO: 73198-78-4
• Molecular Formula: C₉H₂₁NSi
• Molecular Weight: 171.36
• Mol File: 73198-78-4.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 54 °C (12 mmHg)
• Appearance: /
• Refractive Index: 1.425-1.429
• Storage Temp.: 0-6°C
• CAS DataBase Reference: 2-TRIMETHYLSILYL-N-TERT-BUTYLACETALDIMINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-TRIMETHYLSILYL-N-TERT-BUTYLACETALDIMINE(73198-78-4)
• EPA Substance Registry System: 2-TRIMETHYLSILYL-N-TERT-BUTYLACETALDIMINE(73198-78-4)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 73198-78-4(Hazardous Substances Data)

Usage

Chemical Properties

clear light yellow to yellow liquid

Upstream product

• 75-64-9 tert-butylamine 
• 1066-54-2 trimethylsilylacetylene 
• 7020-80-6 acetaldehyde N-tert-butylimine 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 472-86-6 13-cis-vitamin A aldehyde 
• 116-31-4 all-trans-Retinal 
• 87322-06-3 C₁₅H₁₉⁽²⁾H₃O 
• 87322-07-4 C₁₅H₁₉⁽²⁾H₃O 
• 1187542-30-8 C₁₆H₃₀O₄Si 
• 136809-07-9 1-tert-butyl-4-phenyl-1-aza-1,3-butadiene 
• 120674-59-1 3-tert-butyldimethylsilyloxy-β-ionylideneacetaldehyde 
• 120674-43-3 3-tert-butyldimethylsilyloxy-β-ionylideneacetaldehyde 
• 87355-48-4 all-E-(20-⁽¹³⁾C)retinal 
• 87355-46-2 (19-(13)C)β-ionylideneacetaldehyde 
• 121468-87-9 (2Z,4E)-5-[(S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enyl]-3-methyl-penta-2,4-dienal 
• 67567-19-5 9-cis-β-ionylidenecrotonaldehyde 
• 6980-79-6 (2E,4E,6E)-5-methyl-7-(2’,6’,6’-trimethylcyclohex-1’-en-1’-yl)-hepta-2,4,6-trienenal 
• 74596-85-3 tert-Butyl-[(E)-3-ethyl-7-methyl-octa-2,6-dien-(E)-ylidene]-amine 

Relevant articles and documents

Anti-Markovnikov Intermolecular Hydroamination: A Bis(amidate) Titanium Precatalyst for the Preparation of Reactive Aldimines

(Matrix presented) A bulky bis-(N-2′,6′- diisopropylphenyl(phenyl)-amidate)titanium-bis(diethylamido) complex was identified as a highly active and regioselective precatalyst for the anti-Markovnikov hydroamination of a wide range of terminal alkyl alkynes with alkylamines. This titanium complex was fully characterized, including its X-ray crystal structure. The reactive aldimine products generated have been further elaborated using one-pot procedures to give substituted amines, aldehydes, and the isoquinoline framework.