73391-84-1

Upstream product

• 780-25-6 N-benzylidene benzylamine 

Downstream Products

• 17040-65-2 1-cyclohexenyl(phenyl)methanone 
• 100-52-7 benzaldehyde 
• 109458-82-4 trans-2-(α-aminobenzyl)-cyclohexanol 
• 100-46-9 benzylamine 
• 109458-81-3 cis-2,4-diphenyl-trans-4a,8a-perhydrobenz-1,3-oxazine 
• 18621-79-9 ((1S*,2S*)-2-hydroxycyclohexyl)(phenyl)methanone 
• 74619-81-1 (E)-N-(1,2-diphenylethyl)-1-phenylmethanimine 

Relevant academic research and scientific papers

The Reaction of Sodium 1,3-Diphenyl-2-azapropenide with 1,2-Epoxycyclohexane

Ring opening of 1,2-epoxycyclohexane by the title aza-allylic anion afforded a mixture of anions, the quenching and subsequent hydrolysis of which gave rise to trans-2-(α-aminobenzyl)cyclohexanol (10) and benzylamine as the basic fraction, and to either 1-benzoylcyclohexene (11) or trans-2-benzoylcyclohexanol (12), cis-2-benzoylcyclohexanol (14), and benzaldehyde as the neutral fraction: the type of ketone obtained depended upon the hydrolytic conditions.The perhydrobenzoxazine (7) was shown to be the precursor of compound (10).Sodium 1,3-diphenyl-2-azapropenide thus behaved both as an α-benzylamine carbanion equivalent and as a benzoyl anion equivalent.