7353-76-6

Basic information

• Product Name: 1-(cyclohex-3-en-1-yl)ethanone
• Synonyms: 1-(Cyclohex-3-en-1-yl)ethanone; 4-Acetylcyclohexene; Ethanone, 1- (3-cyclohexen-1-yl)-; ethanone, 1-(3-cyclohexen-1-yl)-; Ketone, 3-cyclohexen-1-yl methyl
• CAS NO: 7353-76-6
• Molecular Formula: C₈H₁₂O
• Molecular Weight: 124.1803
• Mol File: 7353-76-6.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 180.9°C at 760 mmHg
• Flash Point: 60.4°C
• Density: 0.947g/cm³
• Vapor Pressure: 0.875mmHg at 25°C
• Refractive Index: 1.468
• CAS DataBase Reference: 1-(cyclohex-3-en-1-yl)ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(cyclohex-3-en-1-yl)ethanone(7353-76-6)
• EPA Substance Registry System: 1-(cyclohex-3-en-1-yl)ethanone(7353-76-6)

Safety Data

• Hazardous Substances Data: 7353-76-6(Hazardous Substances Data)

Usage

General Description

1-(cyclohex-3-en-1-yl)ethanone, also known as p-mentha-1,3-dien-7-one, is a chemical compound with the molecular formula C10H14O. It is a colorless to pale yellow liquid with a strong, peppermint-like odor. It is commonly used as a flavoring agent in the food and beverage industry due to its minty taste and aroma. It is also used in the production of perfumes and other scented products. In addition, it has potential medicinal properties and is being studied for its potential use in pharmaceutical formulations. It is important to handle this chemical with care as it can be irritating to the eyes, skin, and respiratory system.

Upstream product

• 689-97-4 3-buten-1-yne 
• 106-99-0 buta-1,3-diene 
• 3299-38-5 4-(diethylamino)butan-2-one 
• 78-93-3 butanone 
• 78-94-4 methyl vinyl ketone 
• 917-64-6 methyl magnesium iodide 
• 100-45-8 3-cyclohexene-1-carbonitrile 
• 15040-97-8 3-acetylcyclohexanone 
• 4771-80-6 1,2,5,6-tetrahydrobenzoic acid 
• 67-56-1 methanol 
• 100-40-3 4-ethenylcyclohexene 
• 21889-88-3 hept-6-en-2-one 
• 100-50-5 3-Cyclohexene-1-carboxaldehyde 
• 57606-87-8 3-cyclohexene-1-carboxaldehyde oxime 

Downstream Products

• 133146-43-7 1-{(1S,3R,4R)-3,4-Bis-[2-(2-ethoxy-ethoxy)-ethoxy]-cyclohexyl}-ethanone 
• 133146-42-6 2-{(1R,3S,4S)-3,4-Bis-[2-(2-ethoxy-ethoxy)-ethoxy]-cyclohexyl}-2-methyl-[1,3]dioxolane 
• 133146-44-8 (1S,2S,4R)-4-(2-Methyl-[1,3]dioxolan-2-yl)-cyclohexane-1,2-diol 
• 84024-47-5 (1R*,3S*,4R*,7S*)-1-(trans-3,trans-4-dihydroxycyclohexyl)-1-phenyl-3-(1-pyrrolidinyl)-1-propanol 
• 84024-47-5 (1R*,3R*,4S*,7S*)-1-(cis-3,cis-4-dihydroxycyclohexyl)-1-phenyl-3-(1-pyrrolidinyl)-1-propanol 
• 84024-47-5 (1R*,3R*,4S*,7R*)-1-(cis-3,cis-4-dihydroxycyclohexyl)-1-phenyl-3-(1-pyrrolidinyl)-1-propanol 
• 84024-47-5 (1R*,3S*,4R*,7R*)-1-(trans-3,trans-4-dihydroxycyclohexyl)-1-phenyl-3-(1-pyrrolidinyl)-1-propanol 
• 84024-57-7 (1R*,7R*)-1-(3-cyclohexenyl)-1-phenyl-3-(1-pyrrolidinyl)-1-propanol 
• 84024-57-7 (1R*,7S*)-1-(3-cyclohexenyl)-1-phenyl-3-(1-pyrrolidinyl)-1-propanol 
• 661467-30-7 1-Cyclohex-3-enyl-3-[(3R,4R)-4-(3-hydroxy-phenyl)-3,4-dimethyl-piperidin-1-yl]-propan-1-one 
• 661467-31-8 3-[1-(3-cyclohex-3-enyl-3(R,S)-hydroxypropyl)-3(R),4(R)-dimethylpiperidin-4-yl]phenol 
• 100-41-4 ethylbenzene 
• 825-18-3 3-(Δ¹-Cyclohexenyl)-butin-(1)-ol-(3) 
• 17264-01-6 4-(1-hydroxyethyl)-1-cyclohexene 

Relevant articles and documents

Solvent-free Diels-Alder reaction in a closed batch system

Solvent-free Diels-Alder reactions were carried out by heating a mixture of a volatile diene, such as 1,3-butadiene, isoprene, or 2,3-dimethyl-1,3- butadiene, and a dienophile, such as methyl vinyl ketone, methyl acrylate, or maleic anhydride, in a closed batch reactor. High yields of Diels-Alder products were obtained without using solvents and catalysts within a short reaction time in most of the reactions. In particular, several reactions of dienophiles with 1,3-butadiene, which is known as a diene with low reactivity because of its gaseous form, also proceeded with high yields of Diels-Alder products in the closed batch reactor under conditions pressured by the reactant vapor. Solvent-free reactions provided high yields compared to reactions in solvent since the reaction heat directly resulted in increasing the reaction temperature and pressure. Energy in the exothermic reaction was used effectively in the closed batch system under solvent-free conditions.

Regioselective epoxidation of different types of double bonds over large-pore titanium silicate Ti-β

Regioselective epoxidation of different types of double bonds located within the cyclic and acyclic parts of bulky olefins has been investigated using large-pore titanium silicate Ti-β in the presence of dilute aqueous H 2O2 as oxidant under mild liquid-phase conditions. Our experimental results revealed that side-chain vinylic double bonds are selectively epoxidized than those in the cyclohexene-ring. The epoxidation tendency of various bulky olefins with different positional and/or geometric isomers over Ti-β follows the order: terminal -CC- > ring -CC- ≈ bicyclic ring -CC- > allylic C - H bond. Unlike 4-vinyl-1-cyclohexene, epoxidation of an equimolar mixture of cyclohexene and 1-hexene under identical conditions using Ti-β exhibits completely different selectivity and product distributions. Steric factor and accessibility of reactants to active Ti-sites are responsible for the observed regioselectivity of bulky alkenes.

Palladium(II)-catalyzed oxidation of terminal alkenes to methyl ketones using molecular oxygen

Palladium(II) acetate catalyzes the aerobic oxidation of terminal alkenes in toluene into the corresponding methyl ketones in the presence of a catalytic amount of pyridine using propan-2-ol as a reductant and molecular oxygen as an oxidant. Two catalytic cycles sharing a Pd(II)-OOH species are proposed. One is the formation of a Pd(II)-H species in the oxidation of propan-2-ol to acetone, followed by reaction with molecular oxygen to give a Pd(II)-OOH species, and the other is peroxypalladation of an alkene with the Pd(II)-OOH species produced to afford a methyl ketone in the presence of H2O2 produced by the former catalytic cycle. The Royal Society of Chemistry 2000.