73686-46-1Relevant articles and documents
Heterogeneous Suzuki-Miyaura coupling of heteroaryl ester: Via chemoselective C(acyl)-O bond activation
Ma, Hongpeng,Bai, Chaolumen,Bao, Yong-Sheng
, p. 17266 - 17272 (2019/06/24)
A site-selective supported palladium nanoparticle catalyzed Suzuki-Miyaura cross-coupling reaction with heteroaryl esters and arylboronic acids as coupling partners was developed. This methodology provides a heterogeneous catalytic route for aryl ketone formation via C(acyl)-O bond activation of esters by successful suppression of the undesired decarbonylation phenomenon. The catalyst can be reused and shows high activity after eight cycles. The XPS analysis of the catalyst before and after the reaction suggested that the reaction might be performed via a Pd0/PdII catalytic cycle that began with Pd0.
A new ketone synthesis by palladium-catalyzed cross-coupling reactions of esters with organoboron compounds
Tatamidani, Hiroto,Kakiuchi, Fumitoshi,Chatani, Naoto
, p. 3597 - 3599 (2007/10/03)
(Chemical Equation Presented) The palladium-catalyzed coupling reaction of 2-pyridyl esters with organoboron compounds is described. The reaction is compatible with various functional groups and proceeds under mild reaction conditions. The coordination of the nitrogen atom to Pd is a key step for efficient reaction.
