73694-77-6Relevant academic research and scientific papers
Theoretical and infrared studies on the conformational isomerism of trans-2-bromo-alkoxycyclohexanes
Silla, Josue M.,Duarte, Claudimar J.,Freitas, Matheus P.,Ramalho, Teodorico C.,Cormanich, Rodrigo A.,Santos, Francisco P.,Tormena, Claudio F.,Rittner, Roberto
, p. 359 - 362 (2011)
The infrared spectra of trans-2-bromo-alkoxycyclohexanes (alcoxy = OMe, OEt, OiPr and OtBu) were obtained for the neat liquid, and the C-Br stretching mode was quantitatively analyzed to give insight about the conformational isomeris
Tribromoisocyanuric acid: A new reagent for regioselective cobromination of alkenes
De Almeida, Leonardo S.,Esteves, Pierre M.,De Mattos, Marcio C. S.
, p. 1515 - 1518 (2007/10/03)
A simple one-step method for the preparation of tribromoisocyanuric acid in good yield (87%) has been developed. The reaction of tribromoisocyanuric acid with alkenes in presence of nucleophilic solvents (MeOH, i-PrOH, AcOH and a mixture of H2O-acetone, 1:5) led to the corresponding β-bromoethers, β-bromoacetates and bromohydrins, in high regioselectivity and good yields (73-98%). Georg Thieme Verlag Stuttgart.
Photo-induced Alkoxybromination of Olefins by N,N'-Dibromo-2,5-piperazinedione
Sera, Akira,Yamada, Hiroshi,Itoh, Kuniaki
, p. 219 - 221 (2007/10/02)
Irradiation of N,N'-dibromo-2,5-piperazinedione in dichloromethane in the presence of an alcohol induced alkoxybromination of cyclohexene to give trans-1-bromo-2-alkoxycyclohexane in a good yield.The reaction was thought to proceed through an ionic mechanism.
