73713-91-4Relevant articles and documents
Silver catalyzed decarboxylative direct C2-alkylation of benzothiazoles with carboxylic acids
Zhao, Wei-Ming,Chen, Xiao-Lan,Yuan, Jin-Wei,Qu, Ling-Bo,Duan, Li-Kun,Zhao, Yu-Fen
supporting information, p. 2018 - 2020 (2014/03/21)
A novel and efficient silver catalyzed decarboxylative direct C2-alkylation of benzothiazoles with carboxylic acids for the synthesis of 2-alkyl benzothiazoles was developed.
A general palladium-catalyzed method for alkylation of heteroarenes using secondary and tertiary alkyl halides
Wu, Xiaojin,See, Jessica Wei Ting,Xu, Kai,Hirao, Hajime,Roger, Julien,Hierso, Jean-Cyrille,Zhou, Jianrong
supporting information, p. 13573 - 13577 (2015/01/09)
A general alkylation of heterocycles using a simple palladium catalyst is reported. Most classes of heterocycles, including indoles and pyridines, efficiently coupled with unactivated secondary and tertiary alkyl halides. An alkyl radical addition to neutral heteroarenes is most likely involved.
Copper-catalyzed alkylation of benzoxazoles with secondary alkyl halides
Ren, Peng,Salihu, Isuf,Scopelliti, Rosario,Hu, Xile
supporting information; experimental part, p. 1748 - 1751 (2012/05/20)
Copper-catalyzed direct alkylation of benzoxazoles using nonactivated secondary alkyl halides has been developed. The best catalyst is a new copper(I) complex (1), and the reactions are promoted by bis[2-(N,N-dimethylamino)ethyl] ether.
Allenes. Part 44. Formation of Oxazolines and Benzoxazoles from Allenic nitriles and amides and from Phenylpropynenitrile.
Fomum, Z. Tanee,Nkengfack, A. Ephrem,Mpango, George W. P.,Landor, Stephen R.,Landor, Phyllis D.
, p. 901 - 924 (2007/10/02)
Michael addition of ethanolamines and 2-aminophenol to allenic nitriles, allenic amides and phenylpropynenitrile gives enaminic nitriles and amides which at 290 deg - 320 deg yield oxazolines and benzoxazoles.
