73853-36-8

Upstream product

• 109-06-8 α-picoline 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 1007107-45-0 (R)-1-(4-methoxyphenyl)-2-( pyridin-2-yl)ethanol 
• 1007107-39-2 C₂₇H₃₃NO₂Si 
• 1227475-53-7 (S)-2-(2-[bis(3,5-dimethylphenyl)methylsilanyloxy]-2-(4-methoxyphenyl)ethyl)pyridine 
• 109-06-8 α-picoline 
• 123-11-5 4-methoxy-benzaldehyde 
• 19036-99-8 2-(4-Methoxy-styryl)-pyridin 

Relevant academic research and scientific papers

Lewis-acid-catalyzed benzylic reactions of 2-methylazaarenes with aldehydes

Lewis-acid-catalyzed benzylic reactions of 2-methylazaarenes with aldehydes have been investigated. Series of azaarene derivatives were afforded by this reaction. 2-(Pyridin-2-yl)ethanols with common substituents were formed through the LiNTf2-promoted aldol reaction for the first time. 2-Alkenylpyridines, exclusively in the form of the E isomers, were synthesized in the presence of LiNTf2 cooperated with H2NTf. In the presence of La(Pfb)3 as catalysis, 2-alkenylquinolines were obtained in high yields through the reactions between 2-methylquinolines and aldehydes under air.

Catalytic asymmetric Si-O coupling of simple achiral silanes and chiral donor-functionalized alcohols

"Chemical Equation Presented" Biomimetic and efficient: Mixed calcium manganese(III) oxides (see structure; Ca green, Mn red, O white) with elemental compositions and structures mimicking the active site of photosystem II were found to be highly active catalysts for the oxidation of water to molecular oxygen. As for PSII, the presence of Ca2+ greatly enhances the catalyst performance in comparison to the related manganeseonly system Mn2O3.

AN ALDOL-TYPE REACTION OF ACTIVE METHYL GROUPS OF NITROGEN-CONTAINING HETEROAROMATIC COMPOUNDS

Active methyl groups of nitrogen-containing heteroaromatic compounds react with benzaldehydes in the presence of 9-BBN triflate and diisopropylethylamine in dichloromethane to give the corresponding aldol-type products under mild conditions.