73885-72-0

Basic information

• Product Name: Carbamic acid, [(1E)-2-phenylethenyl]-, methyl ester
• CAS NO: 73885-72-0
• Molecular Formula: C10H11NO2
• Molecular Weight: 177.203
• Mol File: 73885-72-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [(1E)-2-phenylethenyl]-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [(1E)-2-phenylethenyl]-, methyl ester(73885-72-0)
• EPA Substance Registry System: Carbamic acid, [(1E)-2-phenylethenyl]-, methyl ester(73885-72-0)

Safety Data

• Hazardous Substances Data: 73885-72-0(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 621-79-4 cinnamamide 
• 84353-56-0 (E)-N-(2-phenylethenyl)-2,2,2-trifluoroacetamide 
• 33066-20-5 (E)-1-isocyanato-2-phenylethene 
• 1722-84-5 (E)-N-styrylacetamide 
• 136354-01-3 N-methoxycarbonyl-1-methoxy-2-phenylethylamine 
• 118653-24-0 methyl(E)-N-formyl-N-(2-phenylethenyl)acetamide 

Downstream Products

• 122-78-1 phenylacetaldehyde 
• 118653-35-3 (S)-2-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-N-((E)-styryl)-propionamide 
• 90289-81-9 Demethoxytuberin 
• 118653-24-0 methyl(E)-N-formyl-N-(2-phenylethenyl)acetamide 
• 1722-84-5 (E)-N-styrylacetamide 
• 186343-35-1 (S)-5-phenyl-1,3-oxazolidine-2-one 
• 74387-38-5 (S)-(+)-N-methoxycarbonyl-2-hydroxy-2-phenylethylamine 
• 118653-26-2 [(S)-2-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-propionyl]-((E)-styryl)-carbamic acid methyl ester 

Relevant articles and documents

Various oxidative reactions with novel ion-supported (diacetoxyiodo) benzenes

The oxidation of secondary alcohols and primary alcohols with two novel ion-supported (diacetoxyiodo)benzenes (IS-DIBs) A and B in the presence of a catalytic amount of 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO) in dichloromethane at room temperature proceeded efficiently to provide the corresponding ketones and aldehydes, respectively, in good yields. The oxidative reaction of N,N-diisopropylbenzylamines with those IS-DIBs was also carried out to generate the corresponding aromatic aldehydes in good yields. In addition, the Hofmann rearrangement of primary amides in methanol under basic conditions and the oxidative 1,2-rearrangement of propiophenones in trimethyl orthoformate under acidic conditions with those IS-DIBs provided the corresponding methyl carbamates and methyl 2-arylpropanoates, respectively, in good yields. Moreover, treatment of acetophenones with those IS-DIBs in the presence of trifluoromethanesulfonic acid in acetonitrile generated the corresponding 5-aryl-2-methyloxazoles in good yields. In those five reactions, the desired products were obtained in good yields with high purity by simple extraction of the reaction mixture with diethyl ether and subsequent removal of the solvent from the extract. Moreover, ion-supported iodobenzenes, which were the co-products derived from IS-DIBs in the present oxidative reactions, were recovered in good yields and could be re-oxidized to IS-DIBs A and B for reuse in the same oxidative reactions.

A convenient method for synthesis of optically active β-hydroxyamines from primary amines through enecarbamates as key intermediates

This report describes a new method to prepare optically active β-hydroxamines starting from primary amines. The method consists of a transformation of N-methoxycarbonylated primary amines to the corresponding enecarbamates utilizing electrochemical oxidat

A facile approach to arylacetaldehydes via polymeric palladium catalyst

Several arylacetaldehydes 5 were synthesized in moderate yields via Heck reaction of acrylamide (1) with substituted iodobenzenes 2 in the presence of the polymeric catalyst (P)-phenyl-(1,10-phenanthroline)-palladium(0) [(P)-ph-phen·Pd(0)] followed by Hofmann reaction and subsequent hydrolysis.