73892-35-0Relevant academic research and scientific papers
Metathesis of Phosphorus-containing Olefins catalysed by a Cyclometallated Aryloxo(chloro)neopentylidene-Tungsten Complex
Leconte, Michel,Jourdan, Isabelle,Pagano, Salvatore,Lefebvre, Frederic,Basset, Jean-Marie
, p. 857 - 858 (1995)
A cyclometallated O,O'-diphenyl aryloxy(chloro)neopentylidene-tungsten complex cyclo(OAr)(CHCMe3)Cl(OEt2) 1 is able to carry out metathesis of phosphorous containing olefins; diallylphenyl phosphane is metathetized intramolecularly to give the corresponding phospholene derivative 2 and allyldiphenyl phosphane gives the corresponding bisphosphane 3.
