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Metathesis of Phosphorus-containing Olefins catalysed by a Cyclometallated Aryloxo(chloro)neopentylidene-Tungsten Complex

DOI: 10.1039/c39950000857

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 857 - 858 (1995)

Update date:2022-08-04

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Authors:

Leconte, MichelLeconte, Michel

Jourdan, IsabelleJourdan, Isabelle

Pagano, SalvatorePagano, Salvatore

Lefebvre, FredericLefebvre, Frederic

Basset, Jean-MarieBasset, Jean-Marie

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Article abstract of DOI:10.1039/c39950000857

A cyclometallated O,O'-diphenyl aryloxy(chloro)neopentylidene-tungsten complex cyclo(OAr)(CHCMe3)Cl(OEt2) 1 is able to carry out metathesis of phosphorous containing olefins; diallylphenyl phosphane is metathetized intramolecularly to give the corresponding phospholene derivative 2 and allyldiphenyl phosphane gives the corresponding bisphosphane 3.

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