Metathesis of Phosphorus-containing Olefins catalysed by a Cyclometallated Aryloxo(chloro)neopentylidene-Tungsten Complex

DOI: 10.1039/c39950000857

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 857 - 858 (1995)

Update date:2022-08-04

Topics:

Authors:

Leconte, Michel

Jourdan, Isabelle

Pagano, Salvatore

Lefebvre, Frederic

Basset, Jean-Marie

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950000857

A cyclometallated O,O'-diphenyl aryloxy(chloro)neopentylidene-tungsten complex cyclo(OAr)(CHCMe3)Cl(OEt2) 1 is able to carry out metathesis of phosphorous containing olefins; diallylphenyl phosphane is metathetized intramolecularly to give the corresponding phospholene derivative 2 and allyldiphenyl phosphane gives the corresponding bisphosphane 3.

Full text of DOI:10.1039/c39950000857

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1,4-bis(diphenylphosphino)-2-butene

Cas No:73892-35-0

R&D Labs maybe for 73892-35-0

Chongqing Werlchem Fine Chemical Co. Ltd

Contact:+86-23-67521957

Address:NO.15,Fortune Road,Yubei District,401121,Chongqing,China
Quhua Zhongxing Refrigeration Technology Co.,Ltd.

Contact:+86-5708886618

Address:318 Bulding 2, No.866 Quhua Rd.,Kecheng District
JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing
Tangshan Wisdom Trading Co.,Ltd

Contact:86 315 2222979

Address:No.41 BeiXinXi Road, Yangguang building 1-1102 , Tangshan, Hebei, China
BOC Sciences

website:https://www.bocsci.com/

Contact:1-631-485-4226

Address:Ramsey Road

Relevant to this article

METALLOID DERIVATIVES FOR SYNTHESIS: MONODERIVATIZATION OF SYMMETRIC DIOLS

Doi:10.1016/S0040-4039(00)71420-1
(1980)
PHOTORESPONSIVE MEMBRANES. REGULATION OF MEMBRANE PROPERTIES BY PHOTOREVERSIBLE cis-trans ISOMERIZATION OF AZOBENZENES

Doi:10.1246/cl.1980.421
(1980)
Studies on the Synthesis of Heterocyclic Compounds. Part 875. The Total Stereoselective Retro Mass Spectral Synthesis of (+/-)-Emetine

Doi:10.1039/P19810000920
(1981)
Design, Synthesis, and Biological Evaluation of Quercetagetin Analogues as JNK1 Inhibitors

Doi:10.1002/chem.201502475
(2015)
Synthesis and biological activity of a ketomethylene analogue of a tripeptide inhibitor of angiotensin converting enzyme

Doi:10.1021/jm00186a020
(1980)
Gold-Catalyzed Intermolecular Formal [4 + 2 + 2]-Cycloaddition of Anthranils with Allenamides

Doi:10.1021/acs.orglett.0c02083
(2020)

Article Doi