73908-41-5Relevant academic research and scientific papers
Low temperature hydrodeoxygenation of phenols under ambient hydrogen pressure to form cyclohexanes catalysed by Pt nanoparticles supported on H-ZSM-5
Ohta, Hidetoshi,Yamamoto, Kentaro,Hayashi, Minoru,Hamasaka, Go,Uozumi, Yasuhiro,Watanabe, Yutaka
, p. 17000 - 17003 (2015/11/27)
The hydrodeoxygenation of various phenols to form cyclohexanes was achieved at 110 °C under an H2 atmosphere at ambient pressure using a Pt/H-ZSM-5 catalyst and octane as the solvent.
Stereoelectronic Effects in Hydrogen-atom Transfer Reactions of Substituted Cyclohexyl Radicals
Beckwith, Athelstan L. J.,Easton, Christopher J.
, p. 661 - 668 (2007/10/02)
Thermolysis of the peroxyoxalates (1)-(7) and the diacyl peroxides (8)-(11) in cyclohexane at 100 deg C gives cycloalkenes and cycloalkanes by hydrogen-atom transfer reactions of the initially formed conformationally biased 4-t-butyl-, 4-t-butyl-cis,cis-2,6-dimethyl-, 4-t-butyl-cis,trans-2,6-dimethyl-, 4-t-butyl-cis-2-methyl-, 4-t-butyl-trans-2-methyl-, and 5-t-butyl-cis-2-methylcyclohexyl radicals (12)-(17).The composition of the product mixtures indicates that transfer of axial β-hydrogen atoms occurs more rapidly than does transfer of equatorial β-hydrogen atoms.These results support the hypothesis that homolytic fission of a C-H bond is favoured when it lies chlose to the plane of an adjacent semi-occupied orbital.
