74209-73-7

Basic information

• Product Name: Cyclohexanone, 2-[(R)-methoxyphenylmethyl]-, (2R)-rel-
• CAS NO: 74209-73-7
• Molecular Formula: C14H18O2
• Molecular Weight: 218.296
• Mol File: 74209-73-7.mol
• Article Data: 29

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-[(R)-methoxyphenylmethyl]-, (2R)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-[(R)-methoxyphenylmethyl]-, (2R)-rel-(74209-73-7)
• EPA Substance Registry System: Cyclohexanone, 2-[(R)-methoxyphenylmethyl]-, (2R)-rel-(74209-73-7)

Safety Data

• Hazardous Substances Data: 74209-73-7(Hazardous Substances Data)

Upstream product

• 421-20-5 Methyl fluorosulfonate 
• 13161-18-7 erythro-2-(α-hydroxybenzyl)cyclohexanone 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 42052-56-2 threo-2-(α-hydroxybenzyl)cyclohexanone 
• 100-52-7 benzaldehyde 
• 21300-30-1 lithium 1-cyclohexenolate 
• 42052-56-2 (+/-)-(S,R)-2-[(hydroxy)(phenyl)methyl]cyclohexanone 
• 13161-18-7 2-[hydroxy(phenyl)methyl]cyclohexanone 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 931-57-7 1-methoxy-cyclohex-1-ene 
• 108-94-1 cyclohexanone 
• 35364-99-9 α-chlorobenzyl methyl ether 
• 94358-78-8 C₁₉H₃₀O₃Si 
• 124006-50-4 4-(Cyclohex-1-enyloxy)-4-methyl-4,5-dihydro-3H-4-sila-cyclohepta[2,1-a;3,4-a']dinaphthalene 

Relevant articles and documents

Reaction of acetals with various carbon nucleophiles under non-acidic conditions: C-C bond formation via a pyridinium-type salt

Mild substitution reactions of acetals with carbon nucleophiles via the pyridinium-type salts generated by the treatment of acetals with TESOTf-2,4,6-collidine or 2,2′-bipyridyl have been developed. Various carbon nucleophiles, such as organocuprates, sil

Lewis acid catalyst free electrophilic alkylation of silicon-capped π donors in 1,1,1,3,3,3-hexafluoro-2-propanol

(Figure Presented) A credit to donation: A diverse range of electrophilic addition reactions, conventionally carried out using Lewis acid catalysts, have been performed in electrophilic media without acidic reagents. 1,1,1,3,3,3-Hexafluoro-2-propanol (HFIP) acts as an efficient hydrogen-bond donor and highly polar solvent for a wide range of substrates in reactions with Si-capped π donors.

Carbon-carbon bond forming reactions by using bistrifluoromethanesulfonimide

Bistrifluoromethanesulfonimide has been used to catalyze C-C bond forming reactions such as Friedel-Crafts, Mukaiyama, 1,2-addition and 1,4-addition as well as C-glycosidation reactions.