74252-96-3Relevant academic research and scientific papers
Visible light promoted thiol-ene reactions using titanium dioxide
Bhat, Venugopal T.,Duspara, Petar A.,Seo, Sangwon,Abu Bakar, Nor Syazwani Binti,Greaney, Michael F.
, p. 4383 - 4385 (2015)
The radical addition of thiols to alkenes is reported under photoredox conditions, using visible light and TiO2 as a cheap and readily available photocatalyst.
One-Flask Synthesis of Sulfides from Alcohols and Alkyl Halides Using Benzoxazoline-2-thione
Takeuchi, Yasuo,Sakagawa, Keiko,Kubo, Masumi,Yamato, Masatoshi
, p. 1323 - 1327 (2007/10/02)
The synthesis of sulfides from alcohols and benzoxazoline-2-thione (I) was studied to establish its generality and the mechanism of the reaction.A one-flask synthesis of sulfides from alcohols was developed.According to this procedure, various sulfides were prepared without the use of illsmelling thiols.Moreover, partial sulfenylation of diols to give sulfenyl alcohols was achieved.Keywords - one-flask synthesis; benzoxazoline-2-thione; partial sulfenylation; sulfide; sulfenyl alcohol
SULFUR PARTICIPATION IN SOLVOLYSIS INVOLVING FOUR-MEMBERED RING INTERMEDIATES
Eliel, Ernest L.,Pearson, William H.,Jewell, Linda M.,Abatjoglou, Anthony C.,Kenan, William R.
, p. 331 - 334 (2007/10/02)
Neighboring group participation via four-membered ring intermediates resulting in complete rearrangement occurs in the methanolysis of R1R2C(SCH2C6H5)CH2CH(R3)OTs when R1=R2=R3=Me and when R1=R2=Me, R3=H.No rearrangement is found for R1=R2=R3=H or R1=R2=H, R3=Me.The case of R1=Me, R2=R3=H is intermediate.
