74376-28-6

Upstream product

• 7442-11-7 N,N-diethyl-N'-phenylthiourea 
• 2009-97-4 ethyl 2-diazo-3-oxobutanoate 
• 103-72-0 phenyl isothiocyanate 
• 705-62-4 N,N-dimethyl-N'-phenylthiourea 
• 609-15-4 ethyl 2-chloro-3-oxo-butyrate 
• 81852-22-4 ethyl cyano<thio>acetate 

Downstream Products

• 124-38-9 carbon dioxide 
• 16156-85-7 ethyl 4-methyl-2-phenyl-Δ⁴-thiazoline-5-carboxylate 
• 102-08-9 N,N-diphenylthiourea 
• 463-58-1 carbon oxide sulfide 

Relevant academic research and scientific papers

Formation of 2-Imino-1,3-oxathioles and 2(3H)-Oxazolethione by the Rhodium(II) Acetate-Catalyzed Reaction of α-Diazocarbonyl Compounds with Isothiocyanates

The rhodium(II) acetate-catalyzed reaction of various α-diazocarbonyl compounds with alkyl, phenyl, and benzoyl isothiocyanates gave 2-imino-1,3-oxathioles in good yields. 2(3H)-Oxazolethione was obtained as a byproduct only in the reaction of diazodimedo

Reactions of Monoprotic Thioureas with Ethyl α-Chloroacetoacetate, Ethyl Bromomalonate, and Ethyl Bromocyanoacetate

N,N,-Dialkyl-N'-arylthioureas (1) with ethyl α-chloroacetoacetate, furnished dialkylamine hydrochlorides, aryl isothiocyanates, 2-arylimino-1,3-oxathioles (2), 2-arylimino-3-aryl Δ4-thiazolines (3), diarylthioureas (9), and carbonyl sulphide.With ethyl bromomalonate the products were dialkylamine hydrobromides, aryl isothiocyanates, 2-arylimino-3-arylthiazolidin-4-ones (11), and diarylthioureas (9).Ethyl bromocyanoacetate gave an ethyl cyanothio>acetate (13).Compound (13) with triethylamine gave the starting thiourea (1) and diethyl dicyanofumarate.