744-38-7Relevant articles and documents
Mercury (II) sensing via cyclization of a dithioamide into a benzimidazole derivative: A structural and spectroscopic study
Chakraborty, Indranil,Fasiku, Adenike O.,Fortunato, Matthew T.,Kavallieratos, Konstantinos
, (2020)
An o-phenylenediamine-derived dithioamide L was found to sense Hg(II) in the UV–visible via Hg(II)-mediated cyclization leading to a new benzimidazole derivative (L′). Both L and L′ have been characterized by single-crystal X-ray crystallography. The stru
QUANTITATIVE CHIRALITY AND CONCENTRATION SENSING OF CHIRAL ANALYTES USING A RELAY ASSAY
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Paragraph 0136, (2021/11/13)
The present application relates to an analytical method that includes providing a sample potentially containing a chiral analyte that can exist in stereoisomeric forms, providing certain probes; and providing an indicator. The sample is contacted with an
Quantitative Chirality and Concentration Sensing of Alcohols, Diols, Hydroxy Acids, Amines and Amino Alcohols using Chlorophosphite Sensors in a Relay Assay
Balaraman, Kaluvu,Thanzeel, F. Yushra,Wolf, Christian
supporting information, p. 21382 - 21386 (2020/09/21)
Analytical methods that allow simultaneous determination of the concentration and enantiomeric composition of small sample amounts and are also compatible with high-throughput multi-well plate technology have received increasing attention in recent years. We now introduce a new class of broadly useful small-molecule probes and a relay sensing strategy that together accomplish these tasks with five classes of compounds including the challenging group of mono-alcohols—a scope that stands out among previously reported UV, fluorescence, and CD assays. Several chlorophosphite probes and aniline indicators have been evaluated and used for on-the-fly CD/UV sensing following a continuous workflow. The wide application range of the readily available sensors is highlighted with almost 30 alcohols, diols, hydroxy acids, amines and amino alcohols, and the accuracy of the stereochemical analysis is showcased with samples covering a wide range of concentrations and enantiomeric ratios.