74510-40-0

Upstream product

• 39538-68-6 2-methoxy-4-methylaniline 
• 3282-30-2 pivaloyl chloride 
• 98922-98-6 2'-hydroxy-2,2,4'-trimethylpropionanilide 
• 74-88-4 methyl iodide 
• 2835-98-5 2-Hydroxy-4-methylanilin 

Downstream Products

• 80389-40-8 3-methoxy-5-methyl anthranilic acid 
• 74510-41-1 2-(2,2-Dimethyl-propionylamino)-3-methoxy-5-methyl-benzoic acid 
• 869554-52-9 methyl 2-(2-benzenesulfonylvinyl)-3-methoxy-5-methylbenzoate 
• 1253779-04-2 N-(2-methoxy-4-((N-(phenylsulfonyl)phenylsulfonamido)methyl)phenyl)pivalamide 
• 115475-74-6 methyl-3-methoxy-5-methyl anthranilate 
• 74510-47-7 {2-Chloro-3-methoxy-5-[2-methyl-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-but-3-enyl]-phenyl}-methyl-carbamic acid methyl ester 
• 74510-51-3 {(E)-4-[4-Chloro-3-methoxy-5-(methoxycarbonyl-methyl-amino)-phenyl]-3-methyl-but-2-enyl}-phosphonic acid diethyl ester 
• 74510-50-2 [2-Chloro-5-((E)-4-iodo-2-methyl-but-2-enyl)-3-methoxy-phenyl]-methyl-carbamic acid methyl ester 
• 74510-46-6 (5-Bromomethyl-2-chloro-3-methoxy-phenyl)-methyl-carbamic acid methyl ester 
• 74510-45-5 (2-Chloro-3-methoxy-5-methyl-phenyl)-methyl-carbamic acid methyl ester 
• 74510-44-4 (2-Chloro-3-methoxy-5-methyl-phenyl)-carbamic acid methyl ester 
• 74510-43-3 2-Chloro-3-methoxy-5-methyl-benzoic acid 
• 90605-50-8 [5-((E)-4-Bromo-2-methyl-but-2-enyl)-2-chloro-3-methoxy-phenyl]-methyl-carbamic acid methyl ester 
• 90605-47-3 [2-Chloro-5-((E)-4-hydroxy-2-methyl-but-2-enyl)-3-methoxy-phenyl]-methyl-carbamic acid methyl ester 

Relevant academic research and scientific papers

Remote amide-directed palladium-catalyzed benzylic C-H amination with N-fluorobenzenesulfonimide

An unprecedented remote amide-directed palladium-catalyzed intermolecular highly selective benzylic C-H amination with N-fluorobenzenesulfonimide is developed, which represents the first direct benzylic C-H amination with a non-nitrene nitrogen source. This methodology provides a novel approach to circumvent the common ortho aromatic C-H selectivity in directed palladium catalyzed C-H functionalization.

A brief and convergent synthetic route to defucogilvocarcin M chromophore: The formal synthesis of WS-5995 A and C

Densely substituted styryl sulfone 20 is shown to undergo double annulation with phthalide 21 to give, in one-pot operation and in excellent yield, the benzonaphthopyranone scaffold 22 of gilvocarcins.

Synthesis of The Gilvocarcin-M Aglycone

The synthesis of the aglycone of the antibiotic Gilvocarcin-M by a sequential Meerwein Diels-Alder route is reported.The D-ring of the aglycone is attached by a halogen atom directed Meerwein arylation reaction and the A-ring is attached by a halogen atom directed Diels-Alder reaction.In the key step the directing chlorine atom is removed by a new thiophenylation reduction sequence.

Synthesis of maytansinoids: the aromatic moiety of maytansine

A simple and novel synthesis of the tetrasubstituted aromatic compound related to the "western-southern" region of maytansine has been achieved.