74639-51-3

Upstream product

• 67376-72-1 (2R,3S)-3,4-dimethyl-2-phenylperhydro-1,4-oxazepine-5,7-dione 
• 74639-50-2 N-benzyloxycarbonyl-indole-3-carbaldehyde 
• 74639-51-3 3-[(2R,3S)-3,4-Dimethyl-5,7-dioxo-2-phenyl-[1,4]oxazepan-(6Z)-ylidenemethyl]-indole-1-carboxylic acid benzyl ester 
• 501-53-1 benzyl chloroformate 
• 487-89-8 Indole-3-carboxaldehyde 

Downstream Products

• 214541-53-4 (S)-3-(3-indolyl)butanoic acid 
• 21200-24-8 (5S)-5-[(1R)-1-(1H-indol-3-yl)ethyl]-2-methylamino-2-oxazolin-4-one 
• 74639-51-3 3-[(2R,3S)-3,4-Dimethyl-5,7-dioxo-2-phenyl-[1,4]oxazepan-(6E)-ylidenemethyl]-indole-1-carboxylic acid benzyl ester 

Relevant academic research and scientific papers

ASYMMETRIC TOTAL SYNTHESIS OF INDOLMYCIN

An asymmetric total synthesis of indolmycin was achieved via a key intermediate, α-indolmycenic acid ester.The ester was obtained by oxygenation of methyl (S)-3-(3-indolyl)butanoate which was prepared by asymmetric synthesis utilizing (2R,3S)-3,4-dimethyl