7475-15-2Relevant academic research and scientific papers
Oxidative nitration of alkenes with tert-butyl nitrite and oxygen
Taniguchi, Tsuyoshi,Yajima, Atsushi,Ishibashi, Hiroyuki
supporting information; experimental part, p. 2643 - 2647 (2011/11/30)
A method for the oxidative nitration of alkenes using a combination of tert-butyl nitrite and molecular oxygen to give β-nitro alcohols and their nitrate derivatives has been developed. The present reaction provides a practical method for the synthesis of
FORMATION OF NITRO COMPOUNDS DURING THE NITROSATION OF OLEFINS BY ALKYL NITRITES
Yandovskii, V. N.,Ryabinkin, I. I.,Tselinskii, I. V.
, p. 1773 - 1775 (2007/10/02)
Vicinal nitro alcohols and/or dinitro derivatives are formed in the reaction of olefins containing a quaternary carbon atom with alkyl nitrites in acetic acid.
Reduction of 2,2-Diaryl-1-nitroethylenes : New Synthesis of 2,2-Diarylacetaldehydes and 1,1,4,4-Tetraarylbuta-1,3-dienes
Tadros, Wadie,Awad, Sami B.,Sakla, Alfy B.,Abdul-Malik, Nadia F.,Armanious, Emili R.
, p. 199 - 202 (2007/10/02)
2,2-Diarylacetaldehydes (VII) have been obtained by selective and controlled reduction of 2,2-diaryl-1-nitroethylenes (IV) in acid medium, and also by acid hydrolysis of 2,2-diarylvinyl-N-acetamides (VI).Nitroalkenes (IV) have been prepared by the reaction of 2,2-diarylethylenes (I) with nitrous acid whereas N-acetamide derivatives (VI) have been obtained by reductive acetylation of the nitro compounds (IV).A number of 1,1,4,4-tetraarylbuta-1,3-dienes (XI) have been obtained by the condensation of 2,2-diarylacetaldehydes (VII) with appropriate 2,2-diarylethylenes (I).Structures of the products have been assigned on the basis of analytical data and chemical and spectral evidences.
