74839-03-5

Upstream product

• 105-50-0 diethyl 1,3-acetonedicarboxylate 
• 52887-35-1 Ethyl 4-benzyloxycarbonyl-3-ethoxycarbonylmethyl-5-methylpyrrole-2-carboxylate 

Downstream Products

• 54474-50-9 2,4-dimethyl-3-pyrrolepropanoic acid 
• 2436-79-5 diethyl 2,4-dimethylpyrrole-3,5-dicarboxylate 
• 6122-77-6 3-ethoxycarbonylmethyl-4-formyl-5-methyl-pyrrole-2-carboxylic acid ethyl ester 
• 62562-74-7 benzyl 4-<<(benzyloxy)carbonyl>methyl>-2-methylpyrrole-5-carboxylate 
• 130912-61-7 1-Bromo-3,8,13-triethyl-17-(methoxycarbonyl)methyl-2,7,12,19-tetramethylbiladiene-ac dihydrobromide 
• 84089-80-5 Benzyl 3-(methoxycarbonyl)methyl-5-methylpyrrole-2-carboxylate 
• 87377-74-0 benzyl 3-(methoxycarbonylmethyl)-4'-(ethoxycarbonylmethyl)-3',4-dimethyl-5'-ethoxycarbonylpyrromethane-5-carboxylate 
• 87377-72-8 dibenzyl 3'-(2-chloroethyl)-4-(2-acetoxyethyl)-3,4'-dimethylpyrromethane-5,5'-dicarboxylate 
• 87377-71-7 C₃₁H₃₃ClN₂O₅ 
• 87377-75-1 benzyl 3,4'-bis-(2-hydroxyethyl)-3',4-dimethyl-5'-ethoxycarbonylpyrromethane-5-carboxylate 
• 87377-64-8 5-benzyloxycarbonyl-4-(2-acetoxyethyl)-3-methylpyrrole-2-carboxylic acid 
• 87377-65-9 benzyl 5-iodo-3-(2-acetoxyethyl)-4-methylpyrrole-2-carboxylate 
• 87377-67-1 5-ethoxycarbonyl-4-(ethoxycarbonylmethyl)-3-methylpyrrole-2-carboxylic acid 
• 87377-66-0 benzyl 3-(2-acetoxyethyl)-4-methylpyrrole-2-carboxylate 

Relevant academic research and scientific papers

Transformation of a monovinylporphyrin to benzoporphyrins via Diels-Alder adducts

A β-unsubstituted-β'-vinylporphyrin has been synthesized which reacted with an excess of acetylenedicarboxylate ester to give monobenzoporphyrins in high yield. Evidence that suggests an isomerization of the initial adduct to a new porphyrin enroute to the benzoporphyrin is presented.