74993-52-5

Basic information

• Product Name: Hydroxylamine, O-(3-methylphenyl)-
• CAS NO: 74993-52-5
• Molecular Formula: C7H9NO
• Molecular Weight: 123.155
• Mol File: 74993-52-5.mol
• Article Data: 21

Chemical Properties

• Boiling Point: 65 °C(Press: 5 Torr)
• Density: 1.053±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Hydroxylamine, O-(3-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Hydroxylamine, O-(3-methylphenyl)-(74993-52-5)
• EPA Substance Registry System: Hydroxylamine, O-(3-methylphenyl)-(74993-52-5)

Safety Data

• Hazardous Substances Data: 74993-52-5(Hazardous Substances Data)

Upstream product

• 937716-84-2 N-(3-methyl)phenoxyphthalimide 
• 17933-03-8 m-tolylboronic acid 
• 1239023-69-8 C₂₆H₁₅F₁₇N₂O₄ 
• 108-39-4 3-methyl-phenol 

Downstream Products

• 2835-97-4 2-amino-3-methylphenol 
• 95-71-6 2-methylbenzene-1,4-diol 
• 2835-98-5 2-Hydroxy-4-methylanilin 
• 452-86-8 4-methyl-1,2-dihydroxybenzene 
• 488-17-5 3-methylbenzene-1,2-diol 
• 39267-61-3 2,2,2-trifluoro-N-(2-hydroxy-4-methylphenyl)acetamide 
• 937716-65-9 (E)-1-phenylethanone O-(3-methylphenyl)oxime 
• 14770-90-2 2,3-diphenyl-6-methylbenzofuran 
• 1443440-55-8 N-(m-tolyloxy)acetamide 
• 39720-17-7 2-(2'-hydroxy-4'-methylphenyl)benzoxazole 
• 3098-18-8 2-hydroxy-4-methylbenzophenone 
• 13429-10-2 N-(2-hydroxy-4-methylphenyl)acetamide 

Relevant articles and documents

An Activity-Based Sensing Fluorogenic Probe for Monitoring Ethylene in Living Cells and Plants

Ethylene (ET) is an important gaseous plant hormone. It is highly desirable to develop fluorescent probes for monitoring ethylene in living cells. We report an efficient RhIII-catalysed coupling of N-phenoxyacetamides to ethylene in the presenc

Synthesis of ortho-phenolic sulfilimines via an intermolecular sulfur atom transfer cascade reaction

To expand the toolbox for the synthesis of ortho-phenolic sulfilimines, sigmatropic rearrangements were introduced to the field of sulfilimine chemistry. Herein we report a N-H sulfenylation/[2,3]-sigmatropic rearrangement cascade reaction. This mild reaction enables commercially available thiols to serve as the sulfenylation reagent and generates water as the sole byproduct. Moreover, the reaction has a wide substrate scope and can be conducted on a gram scale with excellent reaction efficiency.

RhIII-Catalyzed Decarboxylative o-Acylation of Arenes Bearing an Oxidizing Directing Group

Here in we report, rhodium(III)-catalyzed decarboxylative acylation of arenes using α-oxocarboxylic acids as acyl surrogate. In this strategy, O–NHAc group act as an autocleavable oxidizing directing group (ODGauto), thus giving rise to ortho-acylated phenols in moderate to good yields. Mechanistic studies provided strong support for a kinetically relevant C–H bond activation. According to the best of our knowledge, this is the first report of Rhodium catalyzed decarboxylative acylation.